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H2S is more acidic than H2O. The reason ...

`H_2S` is more acidic than `H_2O`. The reason is

A

`O-H` bond is stronger than `S-H` bond

B

`O` is more electronegative than S

C

`H-S` bond is stronger than `O-H` bond

D

`O-H` bond is weaker than `H-S` bond

Text Solution

Verified by Experts

The correct Answer is:
A

To release `H^(+)` (proton), the `H-E` (E stands for element which may be O or S) bond must be broken. On account of relatively large size of S atom, the `H-S` bond is weaker than the `O-H` bond and, hence, easy to break.
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Knowledge Check

  • H_(2) S is move acidic than H_(2)O . The reason is

    A
    O-H bond is stronger than S-H bond
    B
    O is more electronegative than sulphur
    C
    H-S bond is weaker than O-H bond
    D
    O-H bond is weaker than H-S bond
  • Assertion (A) : H_2S is more acidic than H_2O . Reason (R) :H-S bond is more polar than H-O bond.

    A
    Both A and R true and R is the correct explanation of A
    B
    Both A and R true and R is not a correct explanation of A
    C
    A is true but R is false
    D
    A is false but R is true
  • Assertion : H_(2)S is stronger acid than PH_(3) . Reason : S is more electronegative than P, conjugate base HS^(− ) is more stable than H_(2)P^(−) .

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
  • Similar Questions

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    Assertion: N_(2)O_(5) is more acidic than P_(4)O_(10) Reason: Nitrogne is more non-metallic than phosphorous.

    Assertion (A) : Ph overset (o+) (N_2) Br^(Θ) is more acidic than NH_4 Br . Reason (R ) : Ph overset (o+)(N)H_(3) (anilinum ion ) is resonance stabilinsed .