Home
Class 12
CHEMISTRY
KCl cannot be used as a salt bridege for...

`KCl` cannot be used as a salt bridege for the cell
`Cu(s)|CuSO_(4)(aq.)||AgNo_(3)(aq.)|Ag(s)`
because

A

`Cl_(2)` gas is evolved

B

`CuCl_(2)` gets precipitated

C

`SO_(2)` gas is evolved

D

`AgCl` gets precipitated

Text Solution

Verified by Experts

The correct Answer is:
C

In this notation, the anode (or oxidation half-cell) is always written first on the lect white the cathode (or reduction half-cell) is always written last on the rifht. The other components appear in the order in which we would encounter them in moving form the anode to the cathode. The two electrodes are electrically connected by means of a slat bridge, denoted by two by vertical bars.
The cell terminals are at the extreme ends in this cell notation. and a single cerical bar indicates a phase boundary-sat between a solid terminal and the electrode solution. for example, the zinc electode is a solild while the `Zn^(2+)` ions (form `ZnSO_(4)`) are in solution. thus, we draw a line between `Zn` and `Zn^(2+)` to show the phase boundries. Note that there is also a line between the `ZnSO_(4)` solution and the `KCl` solution in the salt bridge because these two solutions are not mixed physically and therefore constitute two separate phases.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 4|10 Videos
  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 5|13 Videos
  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 2|6 Videos
  • COORDINATION COMPOUNDS

    R SHARMA|Exercise Archives|56 Videos
  • GENERAL PRINCIPALS AND ISOLATION OF ELEMENTS

    R SHARMA|Exercise Arechives|16 Videos

Similar Questions

Explore conceptually related problems

Can we use KCI as electrolyte in the salt bride of the cell Cu (s) | Cu^(2+) (aq)|| ag^(+)(aq)|Ag(s) ?

Can we use KCI as electrolyte in the salt bride of the cell Cu (s) | Cu^(2+) (aq)|| ag^(+)(aq)|Ag(s) ?

Knowledge Check

  • KCl cannot be used as a salt bridge for all the cell Cu(s) | CuSO_(4) (aq) | | AgNO_(3) (aq) |Ag(s) because

    A
    `CuCl_(2)` gets precipitated
    B
    `Cl_(2)` gas is evolved
    C
    `AgCl` gets precipitated
    D
    None of the above .
  • KCl cannot be used as a salt bridge for cell Cu(s)| CuSO_(4)(aq)| |AgNO_(3)(aq)| Ag(s) because

    A
    `CuCl_(2)` gets precipited
    B
    `Cl_(2)` gas is evolved
    C
    AgCl gest precipitated
    D
    None of the above
  • KCl cannot be used as a salt bridge for the cell Cu(s) abs(CuSO_(4)(aq))abs(AgNO_(3)(aq)) Ag(s) because:

    A
    `CuCl_(2)` gets precipitated
    B
    `Cl_(2)` gas is evolved
    C
    `AgCl` gets precipitated
    D
    None of these
  • Similar Questions

    Explore conceptually related problems

    Calculating the thermodynamic equilibrium constant from the cell emf : The standard emf for the following galvanic cell is 0.46 V Cu(s)|Cu^(2+)(aq.)||Ag^(+)(aq.)|Ag(s) Calculate the equilibrium cosntant K_(C) for the reaction Cu(s)+2Ag^(+)(aq.)hArr Cu^(2+)(aq.)+2Ag(s) Strategy : Substitute the standard emf into the Equation (3.9) realting this quantity to the thermodynatmic equilibrium constant, K_(eq.). Solve K_(eq.). Note that K_(eq.). = K_(C^(.))

    The cell reaction of the galvanic cell Cu(s)|Cu^(2+)(aq)||Hg^(2+)(aq)|Hg(l) is

    The cell reaction of the galvanic cell: Cu(s)|Cu^(2+)(aq)||Hg^(2+)(aq)|Hg(l) is

    Select the correct cell reaction of the cell Pt(s)|Cl_2(g)|Cl^(-)(aq)"||"Ag^+(aq)|Ag(s) :

    Calculate the emf of the following cell: Cu(s)|Cu^(2+) (aq)||Ag^(+) (aq)| Ag(s) Given that, E_(Cu^(2+)//Cu)^(@)=0.34 V, E_(Ag//Ag^(+))^(@)=-0.80 V