Home
Class 12
CHEMISTRY
The logarithm of the equilibriium const...

The logarithm of the equilibriium constant of the cell reaction corresponding to the cell
`X(s)|x^(2+)(aq)||Y^(+)(aq)|Y(s)` with standard cell potential `E_(cell)^(@)=1.2V` given by

A

12.5

B

21.5

C

40.6

D

47.2

Text Solution

AI Generated Solution

The correct Answer is:
To find the logarithm of the equilibrium constant (K) for the cell reaction corresponding to the given cell, we can use the Nernst equation. Here’s a step-by-step solution: ### Step 1: Understand the Nernst Equation The Nernst equation relates the standard cell potential (E°) to the cell potential (E) and the reaction quotient (Q): \[ E = E° - \frac{RT}{nF} \ln Q \] At equilibrium, E = 0, and Q becomes the equilibrium constant K. Thus, we can rewrite the equation as: \[ 0 = E° - \frac{RT}{nF} \ln K \] ### Step 2: Rearranging the Equation Rearranging the equation gives: \[ \ln K = \frac{nFE°}{RT} \] ### Step 3: Substitute Values We know: - Standard cell potential, \( E° = 1.2 \, V \) - The number of electrons transferred, \( n = 2 \) (as inferred from the reaction) - The constants: - \( F = 96485 \, C/mol \) (Faraday's constant) - \( R = 8.314 \, J/(mol \cdot K) \) - Temperature \( T \) is typically taken as 298 K (standard conditions). ### Step 4: Calculate \( \ln K \) Substituting the values into the equation: \[ \ln K = \frac{(2)(96485)(1.2)}{(8.314)(298)} \] ### Step 5: Perform the Calculation Calculating the numerator: \[ (2)(96485)(1.2) = 231564 \] Calculating the denominator: \[ (8.314)(298) = 2477.572 \] Now, calculate \( \ln K \): \[ \ln K = \frac{231564}{2477.572} \approx 93.5 \] ### Step 6: Convert \( \ln K \) to \( K \) To find K, we use: \[ K = e^{93.5} \] ### Step 7: Find \( \log K \) To find \( \log K \), we can use the conversion from natural logarithm to base 10 logarithm: \[ \log K = \frac{\ln K}{\ln 10} \] Where \( \ln 10 \approx 2.303 \): \[ \log K \approx \frac{93.5}{2.303} \approx 40.6 \] ### Final Answer The logarithm of the equilibrium constant \( \log K \) for the cell reaction is approximately **40.6**. ---

To find the logarithm of the equilibrium constant (K) for the cell reaction corresponding to the given cell, we can use the Nernst equation. Here’s a step-by-step solution: ### Step 1: Understand the Nernst Equation The Nernst equation relates the standard cell potential (E°) to the cell potential (E) and the reaction quotient (Q): \[ E = E° - \frac{RT}{nF} \ln Q \] At equilibrium, E = 0, and Q becomes the equilibrium constant K. Thus, we can rewrite the equation as: \[ 0 = E° - \frac{RT}{nF} \ln K \] ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET CORNER|32 Videos
  • ELECTROCHEMISTRY

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise Exercise 1|68 Videos
  • D - AND F-BLOCK ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|27 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS|Exercise MHT CET Corner|14 Videos

Similar Questions

Explore conceptually related problems

Write the cell reaction from the cell notation Zn(s)|Zn^(2+)(aq)||Pb^(2+)(aq)|Pb

Write the cell reaction from the cell notation Tl(s)|Tl^(+)(aq)||Sn^(2+)(aq)|Sn(s)

Knowledge Check

  • The logarithm of the equilibrium constant of the cell reaction corresponding to the cell X(s)|X^(2+)(aq)|| Y^(+)|Y(s) with standard cell potential E_("cell")^(@)=1.2V is given by

    A
    12.5
    B
    21.5
    C
    40.5
    D
    47.2
  • The cell reaction of the galvanic cell: Cu(s)|Cu^(2+)(aq)||Hg^(2+)(aq)|Hg(l) is

    A
    `Hg+Cu^(2+)rarrHg^(2+)+ Cu`
    B
    `Hg+Cu^(2+)rarrCu^(+)+Hg^(+)`
    C
    `Cu+HgrarrCuHg`
    D
    `Cu+Hg^(2+)rarrCu^(2+)+Hg`.
  • The cell reaction of the galvanic cell Cu(s)|Cu^(2+)(aq)||Hg^(2+)(aq)|Hg(l) is

    A
    `Hg+Cu^(2+)rarrHg^(2+)+cu`
    B
    `Hg+Cu^(2+)rarrCu^(+)+Hg^(+)`
    C
    `Cu+HgrarrCuG`
    D
    `Cu+Hg^(2+)rarrCu^(2+)Hg`
  • Similar Questions

    Explore conceptually related problems

    Write the cell reaction for the electrochemical cell represented as Zn(s)|Zn^(2+)(aq)||Cu^(2+)(aq)|Cu(s)

    Write down the half cell reactions and cell reaction for Daniell cell. Zn(s)|Zn^(2+)(aq)(1M) || Cu^(2+)(aq)(1M)/Cu(s)

    Select the correct cell reaction of the cell Ag(s)|Ag^+(aq)"||"cu^(2+)(aq)"|"cu(s) :

    If in a galvanic cell, the cell reaction is reversed as Cu(s)|Cu^(2+)(aq)||Zn^(+2)(aq)|Zn the cell potential will be

    Select the correct cell reaction of the cell Pt(s)|Cl_2(g)|Cl^(-)(aq)"||"Ag^+(aq)|Ag(s) :