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The logarithm of the equilibriium const...

The logarithm of the equilibriium constant of the cell reaction corresponding to the cell
`X(s)|x^(2+)(aq)||Y^(+)(aq)|Y(s)` with standard cell potential `E_(cell)^(@)=1.2V` given by

A

12.5

B

21.5

C

40.6

D

47.2

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The correct Answer is:
To find the logarithm of the equilibrium constant (K) for the cell reaction corresponding to the given cell, we can use the Nernst equation. Here’s a step-by-step solution: ### Step 1: Understand the Nernst Equation The Nernst equation relates the standard cell potential (E°) to the cell potential (E) and the reaction quotient (Q): \[ E = E° - \frac{RT}{nF} \ln Q \] At equilibrium, E = 0, and Q becomes the equilibrium constant K. Thus, we can rewrite the equation as: \[ 0 = E° - \frac{RT}{nF} \ln K \] ### Step 2: Rearranging the Equation Rearranging the equation gives: \[ \ln K = \frac{nFE°}{RT} \] ### Step 3: Substitute Values We know: - Standard cell potential, \( E° = 1.2 \, V \) - The number of electrons transferred, \( n = 2 \) (as inferred from the reaction) - The constants: - \( F = 96485 \, C/mol \) (Faraday's constant) - \( R = 8.314 \, J/(mol \cdot K) \) - Temperature \( T \) is typically taken as 298 K (standard conditions). ### Step 4: Calculate \( \ln K \) Substituting the values into the equation: \[ \ln K = \frac{(2)(96485)(1.2)}{(8.314)(298)} \] ### Step 5: Perform the Calculation Calculating the numerator: \[ (2)(96485)(1.2) = 231564 \] Calculating the denominator: \[ (8.314)(298) = 2477.572 \] Now, calculate \( \ln K \): \[ \ln K = \frac{231564}{2477.572} \approx 93.5 \] ### Step 6: Convert \( \ln K \) to \( K \) To find K, we use: \[ K = e^{93.5} \] ### Step 7: Find \( \log K \) To find \( \log K \), we can use the conversion from natural logarithm to base 10 logarithm: \[ \log K = \frac{\ln K}{\ln 10} \] Where \( \ln 10 \approx 2.303 \): \[ \log K \approx \frac{93.5}{2.303} \approx 40.6 \] ### Final Answer The logarithm of the equilibrium constant \( \log K \) for the cell reaction is approximately **40.6**. ---

To find the logarithm of the equilibrium constant (K) for the cell reaction corresponding to the given cell, we can use the Nernst equation. Here’s a step-by-step solution: ### Step 1: Understand the Nernst Equation The Nernst equation relates the standard cell potential (E°) to the cell potential (E) and the reaction quotient (Q): \[ E = E° - \frac{RT}{nF} \ln Q \] At equilibrium, E = 0, and Q becomes the equilibrium constant K. Thus, we can rewrite the equation as: \[ 0 = E° - \frac{RT}{nF} \ln K \] ...
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