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Phenol, C(6)H(5)OH is allowed to react w...

Phenol, `C_(6)H_(5)OH` is allowed to react with diazomethane, `CH_(2)N_(2)`. The product formed is:

A

`C_(6)H_(5)OCH_(3)`

B

C

D

`C_(6)H_(5)CH_(2)OH`

Text Solution

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The correct Answer is:
To determine the product formed when phenol reacts with diazomethane, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are phenol (C₆H₅OH) and diazomethane (CH₂N₂). 2. **Understand the Mechanism**: - Diazomethane (CH₂N₂) has a reactive methylene group (CH₂) that can be involved in nucleophilic substitution reactions. The nitrogen atoms in diazomethane are part of a diazo group, which can leave as nitrogen gas (N₂). 3. **Nucleophilic Attack**: - The oxygen atom in phenol has a lone pair of electrons and is negatively charged due to its electronegativity. This allows it to act as a nucleophile. - The hydrogen atom of the hydroxyl group (–OH) in phenol is slightly positive due to the electronegativity of oxygen. 4. **Formation of an Intermediate**: - The nucleophilic oxygen from phenol attacks the electrophilic carbon in the diazomethane (CH₂), resulting in the formation of a new bond. - This leads to the formation of an intermediate where the hydrogen from the hydroxyl group is transferred to the nitrogen of diazomethane. 5. **Elimination of Nitrogen Gas**: - The bond between the carbon and one of the nitrogen atoms in diazomethane breaks, leading to the release of nitrogen gas (N₂). - The oxygen from phenol now forms a bond with the methyl group (CH₃) from diazomethane. 6. **Final Product**: - The final product of this reaction is methyl phenyl ether, which is represented as C₆H₅OCH₃. ### Conclusion: The product formed when phenol reacts with diazomethane is methyl phenyl ether (C₆H₅OCH₃).

To determine the product formed when phenol reacts with diazomethane, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are phenol (C₆H₅OH) and diazomethane (CH₂N₂). 2. **Understand the Mechanism**: ...
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Knowledge Check

  • C_6H_5CH_2OH is

    A
    Phenol
    B
    Alcohol
    C
    Carbolic acid
    D
    (a) and (c)
  • When ethene is allowed to react with diazomethane is presence of UV is light, the product formed is

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    D
    Methylcyclopropane
  • When ethyl iodide is allowed to reacts with sodium phenolate the product formed is

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    C
    Ethylbenzene
    D
    Ethylphenol
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