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CH(2)OHCH(2)OH on heating with periodic ...

`CH_(2)OHCH_(2)OH` on heating with periodic acid gives

A

`2HCOOH`

B

`overset(CHO)underset(CHO)("| ")`

C

`2CH_(2)O`

D

`2CO_(2)`

Text Solution

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The correct Answer is:
To solve the question of what `CH₂OH-CH₂OH` (ethylene glycol) produces when heated with periodic acid (HIO₄), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compound**: The compound given is ethylene glycol, which has the structure `CH₂OH-CH₂OH`. This is a 1,2-diol (or glycol). 2. **Understanding the Reaction with Periodic Acid**: Periodic acid (HIO₄) is known to cleave 1,2-diols. When a 1,2-diol reacts with periodic acid, it typically results in the cleavage of the carbon-carbon bond between the two hydroxyl groups. 3. **Cleavage of the Diol**: Upon heating ethylene glycol with periodic acid, the bond between the two carbon atoms is broken. Each carbon atom will form a carbonyl group (C=O), and hydroxyl groups (OH) will be added to the adjacent carbon atoms. 4. **Formation of Intermediate**: The initial reaction will yield an unstable intermediate where both carbon atoms are bonded to hydroxyl groups: - `CH₂(OH)-C(OH)₂` (this is not stable). 5. **Elimination of Water**: The unstable intermediate will undergo dehydration (loss of water) to stabilize the structure. This results in the formation of two moles of formaldehyde (HCHO): - `CH₂O` (formaldehyde). 6. **Final Products**: Therefore, the final products of the reaction when ethylene glycol is heated with periodic acid are two moles of formaldehyde. ### Conclusion: When `CH₂OH-CH₂OH` is heated with periodic acid, it gives formaldehyde (HCHO).

To solve the question of what `CH₂OH-CH₂OH` (ethylene glycol) produces when heated with periodic acid (HIO₄), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compound**: The compound given is ethylene glycol, which has the structure `CH₂OH-CH₂OH`. This is a 1,2-diol (or glycol). 2. **Understanding the Reaction with Periodic Acid**: Periodic acid (HIO₄) is known to cleave 1,2-diols. When a 1,2-diol reacts with periodic acid, it typically results in the cleavage of the carbon-carbon bond between the two hydroxyl groups. ...
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Knowledge Check

  • CH_(2)OH.CH_(2)OH on heating with periodic acid gives

    A
    `2CO_(2)`
    B
    `2HCOOH`
    C
    `{:(CHO),("|"),(CHO):}`
    D
    `2HCHO`
  • CH_(2)OH-CH_(2)OH on heating with periodic acid gives:

    A
    `2CO_(2)`
    B
    `2HCOOH`
    C
    `{:("CHO"),("|"),("CHO"):}`
    D
  • CH_(2)OH-CH_(2)OH on heating with periodic acid gives:

    A
    `2CO_(2)`
    B
    `2HCOOH`
    C
    `{:("CHO"),("|"),("CHO"):}`
    D
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