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MnO(4)^(-)+H^(+)+Br^(-) to Mn^(3+)(aq.)+...

`MnO_(4)^(-)+H^(+)+Br^(-) to Mn^(3+)(aq.)+Br_(2)uarr`

A

For disproportionation reaction.

B

For comproportionation reaction.

C

For either intermolecular redox reaction or displacement reaction

D

For either thermal combination redox reaction or thermal decomposition redox reaction.

Text Solution

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The correct Answer is:
To determine the nature of the reaction given by the equation: \[ \text{MnO}_4^{-} + \text{H}^{+} + \text{Br}^{-} \rightarrow \text{Mn}^{3+} + \text{Br}_2 \] we will analyze the oxidation states of the reactants and products. ### Step-by-Step Solution: 1. **Identify the Oxidation States:** - For \(\text{MnO}_4^{-}\): - Manganese (Mn) has an oxidation state of +7 (since the overall charge is -1 and each oxygen is -2). - For \(\text{Br}^{-}\): - Bromine (Br) has an oxidation state of -1. - For \(\text{Mn}^{3+}\): - Manganese (Mn) has an oxidation state of +3. - For \(\text{Br}_2\): - Bromine (Br) in its elemental form has an oxidation state of 0. 2. **Determine Changes in Oxidation States:** - Manganese changes from +7 in \(\text{MnO}_4^{-}\) to +3 in \(\text{Mn}^{3+}\). This is a reduction (decrease in oxidation state). - Bromine changes from -1 in \(\text{Br}^{-}\) to 0 in \(\text{Br}_2\). This is an oxidation (increase in oxidation state). 3. **Classify the Reaction:** - Since one species (Mn) is being reduced and another species (Br) is being oxidized, this reaction is classified as a **redox reaction** (oxidation-reduction reaction). 4. **Check for Other Types of Reactions:** - **Disproportionation Reaction:** This would require a species to be oxidized and reduced simultaneously. This is not the case here. - **Comproportionation Reaction:** This involves two different oxidation states of the same element reacting to form a third state. This does not apply here either. - **Thermal Reaction:** This would involve heat, which is not relevant in this context. 5. **Conclusion:** - The reaction is a redox reaction where \(\text{MnO}_4^{-}\) is reduced to \(\text{Mn}^{3+}\) and \(\text{Br}^{-}\) is oxidized to \(\text{Br}_2\). ### Final Answer: The nature of the reaction is a **redox reaction**. ---
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Balance the following equation in acidic medium by boht oxidation numbr and ion electron methods nad identify the oxidatns and the reductants (i) MnO_(4)^(-)(aq)+C_(2)H_(2)O_(4)(aq) to Mn^(2+)(aq)+CO_(2)(g)+H_(2)O(l) (ii) H_(2)S(aq)+CI_(2)(g) to S(s)+CI^(-)(aq) (iii) MnO_(4)^(-)(aq)+C_(2)H_(5)OH(aq) to Mn^(2+)(aq)+CH_(3)COOH(aq) (iv) Bi(s)+NO_(3)^(-)(aq) to Bi^(3+)(aq)+NO_(2)(g) (v) Cr_(2)O_(7)^(2-)(aq)+c_(2)H_(4)O(aq)to Cr^(3+)(aq)+C_(2)H_(4)O_(2)(aq) (vi) MnO_(4)^(-)(q)+Br^(-)(aq) to Mn^(2+)(q)+Br_(2)(aq) (vii) Cu(Aq)+NO_(3)^(-)(aq) to Cu^(2+)(aq)+NO_(2)(g) (viii) H_(2)S(g)+Fe^(3+)(aq) to Fe^(2+)(aq)+S(s)+H^(+)(aq) (ix) I^(-)(aq)+O_(2)(g)+H_(2)O(l) to I_(2)(aq)+(OH)^(-)(aq) (x) Zn(s)+NO_(3)^(-)(aq)+H^(+)(aq) to Zn^(2)(aq)+N_(2)O(g)+H_(2)O(l) (xi) As(s)+NO_(3)^(-)(aq)+H^(+)(aq) to AsO_(3)^(3-)(aq)+NO_(2)(g)+H_(2)O(l) (xii) MnO_(4)^(-)(aq)+Fe^(2+)(aq) to Mn^(2+)(aq)+Fe^(3)(aq) (xiii) S+HNO_(3) to SO_(2)+NO_(2)+H_(2)O

Balance the following equation in acidic medium by boht oxidation numbr and ion electron methods nad identify the oxidatns and the reductants (i) MnO_(4)^(-)(aq)+C_(2)H_(2)O_(4)(aq) to Mn^(2+)(aq)+CO_(2)(g)+H_(2)O(l) (ii) H_(2)S(aq)+CI_(2)(g) to S(s)+CI^(-)(aq) (iii) MnO_(4)^(-)(aq)+C_(2)H_(5)OH(aq) to Mn^(2+)(aq)+CH_(3)COOH(aq) (iv) Bi(s)+NO_(3)^(-)(aq) to Bi^(3+)(aq)+NO_(2)(g) (v) Cr_(2)O_(7)^(2-)(aq)+c_(2)H_(4)O(aq)to Cr^(3+)(aq)+C_(2)H_(4)O_(2)(aq) (vi) MnO_(4)^(-)(q)+Br^(-)(aq) to Mn^(2+)(q)+Br_(2)(aq) (vii) Cu(Aq)+NO_(3)^(-)(aq) to Cu^(2+)(aq)+NO_(2)(g) (viii) H_(2)S(g)+Fe^(3+)(aq) to Fe^(2+)(aq)+S(s)+H^(+)(aq) (ix) I^(-)(aq)+O_(2)(g)+H_(2)O(l) to I_(2)(aq)+(OH)^(-)(aq) (x) Zn(s)+NO_(3)^(-)(aq)+H^(+)(aq) to Zn^(2)(aq)+N_(2)O(g)+H_(2)O(l) (xi) As(s)+NO_(3)^(-)(aq)+H^(+)(aq) to AsO_(3)^(3-)(aq)+NO_(2)(g)+H_(2)O(l) (xii) MnO_(4)^(-)(aq)+Fe^(2+)(aq) to Mn^(2+)(aq)+Fe^(3)(aq) (xiii) S+HNO_(3) to SO_(2)+NO_(2)+H_(2)O

Knowledge Check

  • Consider the following reaction occuring in basic medium 2MnO_(4)^(-) + Br^(-)(aq) to 2MnO_(2) (s) + BrO_(3)^(-) (aq) How the above reaction can be balanced further ?

    A
    By adding `2 OH^(-)` ions on right side
    B
    By adding one `H_(2)O` molecule to left side
    C
    By adding `2H^(+)` ions on right side
    D
    Both (a) and (b)
  • For the following balanced redox reaction, 2MnO_(4)^(-) + 4H^(+) + Br_(2) hArr 2Mn^(2+) + 2BrO_(3)^(-) + 2H_(2)O . If the molecular weight of MnO_(4)^(-) and Br_(2) are x & y respectively then

    A
    Equivalent weight of `MnO_(4)^(-)` is `(x)/(5)`
    B
    Equivalent weight of `Br_(2) ` is `(y)/(5)`
    C
    Equivalent weight of `Br_(2)` is `(y)/(10)`
    D
    n-factor ratio of `MnO_(4)^(-)` and `Br_(2)` is 2:1
  • I^(-)(aq.)+MnO_(4)^(-)(aq.)overset(H^(+))toX+Mn^(2+)(aq.) I^(-)(aq.)+MnO_(4)^(-)(aq.) underset("weakly "OH^(-))overset("Neutral or")to Y+MnO_(2) MnO_(4)^(-)(aq.)+Mn^(2+)(aq.) overset(ZnSO_(4)) to Z+4H^(+) Product X, Y and Z are respectively.

    A
    `I_(2),IO_(3)^(-),MnO_(2)`
    B
    `IO_(3)^(-),I_(2),MnO_(2)`
    C
    `I_(2),IO_(3)^(-),MnO_(4)^(2-)`
    D
    `IO_(3)^(-),I_(2),MnO_(4)^(2-)`
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