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In salts of polyatomic anion, as polaris...

In salts of polyatomic anion, as polarising power of cation increase, thermal stability of the salt decrease and decomposed species may further undergo redox reaction
Q. Which of the followinng species undergoes non-redox thermal decomposition reaction on heating?

A

`FeSO_(4)`

B

`SnSO_(4)`

C

`H_(2)C_(2)O_(4)`

D

`Na_(2)HPO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
D

`2FeSO_(4) overset(delta)(to)Fe_(2)O_(3)+SO_(2)(uarr)+SO_(3)(uarr)`
`SnSO_(4) overset(Delta)(to)SnO_(2)+SO_(2)(uarr)`
`H_(2)C_(2)O_(4) overset(Delta)(to) CO(uarr)+CO_(2)(uarr)+H_(2)O`
`2Na_(2)P_(2)O_(7)+H_(2)O`
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Arenediazonium salts are more stable than alkanediazonium salts due to dispersal fo the positive charge on the benzene ring. Obviously, electron-donating groups favour diazotisation by retarding the decomposition of diazonium salts to phenyl cation. The high reactivity of arenediazonium salts is due to the excellent leaving ability of the diazo group as N_(2) gas. Q. Which of the following arylamines undergoes diazotisation most readily?

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Knowledge Check

  • In salts of polyatomic anion, as polarising power of cation increases, thermal stability of the salt decreases, and decomposed species may further undergo redox reaction. Q. Which of the following species undergoes non-redox thermal decomposition reaction on heating?

    A
    `FeSO_(4)`
    B
    `SnSO_(4)`
    C
    `H_(2)C_(2)O_(4)`
    D
    `Na_(2)HPO_(4)`
  • In salts of polyatomic anion, as polarising power of cation increase, thermal stability of the salt decrease and decomposed species may further undergo redox reaction Q. Water soluble salt(x) was heated into three products A, B and C and B and C are two different paramagnetic gases. A is red in hot condition, then salt(x) is :

    A
    `Hg(NO_(3))_(2)`
    B
    `FeC_(2)O_(4)`
    C
    `ZnSO_(4)`
    D
    `Pb(NO_(3))_(2)`
  • In salts of polyatomic anion, as polarising power of cation increase, thermal stability of the salt decrease and decomposed species may further undergo redox reaction Q. Water soluble salt(x) was heated into three products A, B and C and B and C are two different paramagnetic gases. A is red in hot condition, then salt(x) is :

    A
    `Hg(NO_(3))_(2)`
    B
    `FeC_(2)O_(4)`
    C
    `ZnSO_(4)`
    D
    `Pb(NO_(3))_(2)`
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