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The compound 'A' with molecular formula ...

The compound 'A' with molecular formula '`C_(4)H_(8)`' is subjected to the hydrogenation oxidation reaction sequence by using `BH_(3)-THF` complex and hydrogen peroxide to give butan-1-ol(B). The compound 'B' on treatment with pyridinium chlorochromate (PPC) gives compound 'C' . Identify the compounds 'A' and 'C'.

A

`CH_(3)-CH_(2)-CH=CH_(2), CH_(3)-CH_(2)-CH_(2)-CHO`

B

`CH_(3)-CH=CH-CH_(3), CH_(3)-underset(O)underset(||)C-CH_(2)-CH_(3)`

C

`CH_(3)-underset(CH_(3))underset(|)C=CH_(2), CH_(3)-underset(CH_(3))underset(|)CH-CHO`

D

`CH_(3)-CH_(2)-CH=CH_(2), CH_(3)-CH_(2)-underset(O)underset(||)C-CH_(3)`

Text Solution

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The correct Answer is:
A
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Knowledge Check

  • A compound A with molecular formula C_(6)H_(10) on oxidation with hot KMnO_(4) gives hexandioic acid. A is

    A
    2-Hexyne
    B
    1,5-Hexadiene
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    D
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  • A compound with molecular formula, C_(4)H_(8)O gives a positive haloform test and a 2, 4-DNP derivative. The compound is

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    B
    `CH_(3)COCH_(2)CH_(3)`
    C
    `(CH_(3))_(2)CHCHO`
    D
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  • An optically active compound A with molecular formula C_(8)H_(14) undergoes catalytic hydrogenation togive meso compound, the structure of (A) is:

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