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Mark the correct statements(s) (1) Man...

Mark the correct statements(s)
(1) Manganeses exhibits `+7` oxidation state
(2) Zinc forms coloured ions
(3) `[CoF_(6)]^(3-)` is diamagnetic
(4) Sc forms `+4` oxidation state
(5) Zn exhibits only `+2` oxidation state

A

1 and 2

B

1 and 5

C

2 and 4

D

3 and 4

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements are correct regarding the given options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement (1): Manganese exhibits +7 oxidation state.** - Manganese (Mn) has an atomic number of 25, with an electronic configuration of [Ar] 3d^5 4s^2. - It can lose all 7 electrons (2 from 4s and 5 from 3d) to achieve a +7 oxidation state. - **Conclusion**: This statement is **correct**. 2. **Statement (2): Zinc forms coloured ions.** - Zinc (Zn) has an atomic number of 30, with an electronic configuration of [Ar] 3d^10 4s^2. - Since the 3d subshell is completely filled (3d^10), there are no unpaired electrons to allow for the formation of colored ions. - **Conclusion**: This statement is **incorrect**. 3. **Statement (3): [CoF6]^(3-) is diamagnetic.** - To find the oxidation state of cobalt in [CoF6]^(3-), we set up the equation: X + 6(-1) = -3, where X is the oxidation state of Co. - Solving gives X = +3, so cobalt is in the +3 oxidation state. - The electronic configuration of Co is [Ar] 3d^7 4s^2. For Co^(3+), it loses 2 electrons from 4s and 1 from 3d, resulting in [Ar] 3d^6. - Fluoride (F^-) is a weak field ligand, meaning it does not cause pairing of electrons. Hence, the 3d^6 configuration will have unpaired electrons. - **Conclusion**: This statement is **incorrect** (it is paramagnetic). 4. **Statement (4): Scandium forms +4 oxidation state.** - Scandium (Sc) has an atomic number of 21, with an electronic configuration of [Ar] 3d^1 4s^2. - The common oxidation states of Sc are +2 and +3, but it does not typically exhibit a +4 oxidation state. - **Conclusion**: This statement is **incorrect**. 5. **Statement (5): Zn exhibits only +2 oxidation state.** - As previously stated, Zn has a configuration of 3d^10 4s^2. It typically loses the 2 electrons from the 4s subshell to form Zn^(2+). - Since the 3d subshell is fully filled, Zn does not exhibit any other oxidation states. - **Conclusion**: This statement is **correct**. ### Final Answer: The correct statements are **(1) and (5)**.

To determine which statements are correct regarding the given options, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement (1): Manganese exhibits +7 oxidation state.** - Manganese (Mn) has an atomic number of 25, with an electronic configuration of [Ar] 3d^5 4s^2. - It can lose all 7 electrons (2 from 4s and 5 from 3d) to achieve a +7 oxidation state. - **Conclusion**: This statement is **correct**. ...
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Knowledge Check

  • Mark the correct statement (s). (1) Manganese exhibits +7 oxidation state (2) Zinc forms coloured ions (3) [CoF_(6)]^(3-) is diamagnetic (4) Sc forms +4 oxidation state (5) Zn exhibits only +2 oxidation state.

    A
    1 and 2
    B
    1 and 5
    C
    2 and 4
    D
    3 and 4
  • Manganese exhibits maximum oxidation state in:

    A
    `K_(2) MnO_(4)`
    B
    `KMnO_(4)`
    C
    `MnO_(2)`
    D
    `Mn_(2) O_4`
  • Which of the following exhibit only + 3 oxidation state ?

    A
    U
    B
    Th
    C
    Ac
    D
    Pa
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