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Why is BiH(3) the strongest reducing age...

Why is `BiH_(3)` the strongest reducing agent amongst all the hydrides of group `15` elements ?

Text Solution

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As we move down the group, the size of the element increases and, therefore, the length of the E-H bond increases and its strength decreases. In other words, as we move down the group, the E-H bond can break more easily to evolve `H_(2)` gas which acts as the reducing agent. Thus, Bi-H bond is the weakest amongst the hydrides of elements of group 15 and hence `BiH_(3)` is the strongest reducing agent.
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Why is the BiH_(3) strongest reducing agent amongst all the hydrides of group 15 ?

Give reasons for the following: (i) Oxygen is a gas but sulphur is a solid. (ii) O_(3) acts as a powerful oxidising agent. (iii) BiH_(3) is the strongest reducing agent amongst all the hydrides of Groups 15 elements.

Knowledge Check

  • The strongest reducing agent amongst all the hydrides of Group 15 element is

    A
    `BiH_(3)`
    B
    `PH_(3)`
    C
    `NH_(3)`
    D
    `AsH_(3)`
  • The strongest reducing agent is

    A
    `HNO_(3)`
    B
    `H_(2)S`
    C
    `H_(2)SO_(3)`
    D
    `SnCl_(2)`
  • The strongest reducing agent is

    A
    `Cl_(2)`
    B
    `Cl^(-)`
    C
    `Br^(-)`
    D
    `I^(-)`
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