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What are the oxidation states of phospho...

What are the oxidation states of phosphorus in the following:
(i)`H_(3)PO_(3)` , (ii)`PCl_(3)` , (iii)`Ca_(3)P_(2)`
(iv)`Na_(3)PO_(4)` , (v)`POF_(3)`

Text Solution

Verified by Experts

(i) Let the oxidation state of P be x.
`{:((i),overset(+1)(H_(3))overset(x)(P)overset(-2)(O_(3))" "therefore" "3(+1)+x+3(-2)=0 or x = +3,(ii),overset(x)(P)overset(-1)(Cl_(3))" "therefore" "x+3(-1)=0 or x = +3),((iii),overset(+2)(Ca_(3))overset(x)(P_(2))" "therefore" "3(+2)+2 xx x = 0 or x = -3,(iv),overset(+1)(Na_(3))overset(x)(P)overset(-2)(O_(4))" "therefore" "3(+1)+x+4(-2)=0 or x = +5),((v),overset(x)(P)overset(-2)(O)overset(-1)(F_(3))" "therefore" "x + 1 (-2)+3(-1)=0 or x = +5,,):}`
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What are the oxidation states of phosphorous in the following : (i) H_3PO_3 (ii) PCl_3 (iii) Ca_3P_2 (iv) Na_3PO_4 (v) POF_3 ?

Calculate the oxidation number of phosphorus in the following species. (a) HPO_(3)^(2-) " " (b) PO_(4)^(3-)

Knowledge Check

  • What are the oxidation states of phosphorus in the following compounds ? H_(3)PO_(2),H_(3)PO_(4),Mg_(2)P_(2)O_(7),PH_(3),HPO_(3)

    A
    `+1, +3, +3, +3, +5`
    B
    `+3, +3, +5, +5, +5`
    C
    `+1, +2, +3, +5, +5`
    D
    `+1, +5, +5, -3, +5`
  • The order of the oxidation state of the phosphorus atom in H_(3)PO_(2), H_(3)PO_(4), H_(3)PO_(3) and H_(4)P_(2)O_(6) is

    A
    `H_(3)PO_(4) gt H_(3)PO_(2) gt H_(3)PO_(3) gt H_(4)P_(2)O_(6)`
    B
    `H_(3)PO_(2) gt H_(3)PO_(3) gt H_(4)P_(2)O_(6) gt H_(3)PO_(4)`
    C
    `H_(3)PO_(3) gt H_(3) PO_(2) gt H_(2)PO_(4) gt H_(4)P_(2)O_(6)`
    D
    `H_(3)PO_(4) gt H_(4)P_(2)O_(6) gt H_(3)PO_(3) gt H_(3)PO_(2)`
  • The order of the oxidation state of the phosphorus atom in H_(3)PO_(2),H_(3)PO_(4),H_(3)PO_(3),andH_(4)P_(2)O_(6) is

    A
    `H_(3)PO_(4)gtH_(3)PO_(2)gtH_(3)PO_(3)gtH_(4)O_(2)O_(6)`
    B
    `H_(3)PO_(2)gtH_(3)PO_(3)gtH_(4)P_(2)O_(6)gtH_(3)PO_(4)`
    C
    `H_(3)PO_(3)gtH_(3)PO_(2)gtH_(3)PO_(4)gtH_(4)P_(2)O_(6)`
    D
    `H_(3)PO_(4)gtH_(4)P_(2)O_(6)gtH__(3)PO_(3)gtH_(3)PO_(2)`
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    What is the oxidation number of phosphorus in H_(3)PO_(2) molecule ?

    What is the oxidation number of phosphorus in H_(3)PO_(2) molecule ?

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    What is the oxdation number of phosphorus in H_(3)PO_(2) molecule ?

    The order of the oxidation state of the phosphorus in H_(3)PO_(2),H_(3)PO_(4),H_(3)PO_(3) and H_(4)P_(2)O_(6) is