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Both O(2) and F(2) stabilize high oxidat...

Both `O_(2) and F_(2)` stabilize high oxidation states but the ability of oxygen to stabilize the higher oxidation state exceeds than that of flrorine. Account for this observation.

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Compounds in the higher oxidation states are more covalent than in lower oxidation states. Since `O^(2-)` ion has larger ionic size (140 pm) than `F^(-)` ion (136 pm), therefore, any element in a higher oxidation state can polarize `O^(2-)` ion more easily than `F^(-)` ion. As a result, oxides are more covalent than fluorides in the higher oxidation states and hence more stable than fluorides.
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How would you account for the following : (i) H_(2)S is acidic than H_(2)O . (ii) The N-O bond in NO_(2)^(-) is shorter than the N-O bond in NO_(3)^(-) . (iii) Both O_(2) and F_(2) stabilize high oxidation states but the ability of oxygen to stabilize the higher oxidation state exceeds that of florine.

Oxygen stablises higher oxidation state because

Why does oxygen cannot exhibit higher oxidation state?

Although flurorine is more electronegative than oxygen, but the ability of oxygen to stabilize higher oxidation states exceeds that of fluorine . Why ?

Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?

The ability of fluorine to stabilize the highest oxidation state due to higher lattice energy can be seen in:

PRADEEP-P-BLOCK ELEMENTS -VERY SHORT ANSWER QUESTIONS
  1. Which of the following compounds has a lone pair of electrons at the c...

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  2. Write the structures of (i) peroxomonosulphric acid and (ii) peroxodis...

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  3. Both O(2) and F(2) stabilize high oxidation states but the ability of ...

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  4. Halogens are highly reactive ? Explain.

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  5. Which of the following exist as diatomic molecules?

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  6. Name the halogen with lowest ionization energy.

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  7. Fluorine is the most reactive of all four common halogens.

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  8. Most of the reactions of fluorine are exothermic. Give reasons.

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  9. Give one chemical method for the preparation of flourine.

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  10. Write the balanced equation for the following reaction. NaCl is heat...

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  11. Write the chemical equation to show that chlorine gas can be obtained ...

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  12. Write a balanced equation for the reaction of Cl(2) with cold and dilu...

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  13. What happens when chlorine gas is passed through a hot concentrated so...

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  14. What happens when iodine reacts with sodium thiosulphate.

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  15. (a) Name the halogen hydracid with highest bond energy. (b) When HI ...

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  16. KHF(2) is known but KHCl(2) is not known. Give reasons.

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  17. HI cannot be prepared by the action of conc. H(2)SO(4) on KI because

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  18. Arrange the following acids in the correct increasing order of their a...

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  19. Which of the hydracids of halogens reacts with glass ?

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  20. Give an example of a disproportionation reaction of F(2) ?

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