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Calculate the crystal field stabilizatio...

Calculate the crystal field stabilization energy and spin only magnetic moment for the following configuration of octahedral complexes.
(i) `d^(3)` (in weak as well as strong ligand field)
(ii) `d^(5)` (in weak as well as strong ligand field)
(iii) `d^(7)` (in weak ligand field)
(iv) `d^(9)` (in weak as well as strong ligand field)

Text Solution

AI Generated Solution

To solve the problem of calculating the Crystal Field Stabilization Energy (CFSE) and the spin-only magnetic moment for the given configurations of octahedral complexes, we will follow a systematic approach for each configuration. ### Step-by-Step Solution: #### (i) For `d^(3)` Configuration: 1. **Weak Field Ligand:** - Electronic configuration: \( t_{2g}^3 \) ...
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Knowledge Check

  • Crystal field stabilization energy for high spin d^4 octahedral complex is

    A
    `-0.6 triangle_circ`
    B
    `-1.8 triangle_circ`
    C
    -1.6 triangle_circ + p`
    D
    `-1.2 triangle_circ`
  • Crystal field stabilization energy for high spin d^4 octahedral complex is

    A
    (a) `-1.8 Delta_0`
    B
    (b) `-1.6 Delta_0+p`
    C
    (c) `-1.2 Delta_0`
    D
    (d) `-0.6Delta_0`
  • Crystal field stabilization energy for high spin d^4 octahedral complex is :

    A
    `-1.8 Delta_0`
    B
    `-1.6 Delta_0 + P`
    C
    `-1.2 Delta_0`
    D
    `-0.6 Delta_0`
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    Explore conceptually related problems

    The value of spin only magnetic moment for one of the following configurations is "2.84BM" .The correct one is: \(d^{8}\) (in weak field ligand) \(d^{4}\) (in weak field ligand) \(d^{3}\) (in weak as well as strong field ligand) \(d^{5}\) (in strong field ligand)

    Velence bond theroy describes the bonding in complexs in terms of coordinate -covalent bond resulting from overlap filled ligand orbitals with vacant metal hybrid orbitals This theory explains magnetic behaviour and geometrical shape of coordination compounds Magnetic moment of a complex compound can be determined experimentally and theoretically by using spin only formula Magnetic moment sqrtn (n+2)BM (where n = No. unpaired electrons) . The value of of spin only magnetic moment for octahedral complex of the following configuration is 2.84BM The correct statement is (a) d^(4) (in weak field ligand) (b) d^(2) (in weak field and in strong field ligand) (c) d^(3) (in weak field and in strong field ligand) (d) d^(5) (in strong field ligand) .

    Metal and Ligands | Crystal Field Stabilization Energy

    Crystal field stabilization energy for high spin d^(4) octahedral complex is

    The strong field ligand is "