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Explain the mechanism of S(N^(1)) and S(...

Explain the mechanism of `S_(N^(1)) and S_(N^(2))` reactions with examples.

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A
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Explain the mechanism of S_(N^(2)) reaction.

Vinyl halides are inert towards both S_(N^(1)) and S_(N^(2)) reactions. Assign reason.

Knowledge Check

  • S_(N^(1))and S_(N^(2)) reactions are

    A
    Both sterespectic
    B
    Both stereoselective
    C
    Stereoselective and Strerepselectfic respectivly
    D
    Stereoselective and Strerepselective respectivly
  • S_(N^(2)) reaction are

    A
    stereoselective as well as atereopecific
    B
    stereoselective but not stereospecific
    C
    stereospecific but not stereoselective
    D
    Neither stereospecific nor stereoselective
  • Rate of S_(N^(1)) reaction is :

    A
    `SgtQgtRgtP`
    B
    `SgtRgtPgtQ`
    C
    `PgtQgtRgtS`
    D
    `SgtRgtQgtP`
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    Distinguish between S_(N^(1))andS_(N^(2)) mechanism.

    The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. S_(N)1 reaction of optically active alkyl halides leads to

    The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. An S_(N)2 reaction at an asymmetric carbon of a compound always gives

    The polarity of the carbon-halogen bond is responsible for the nucleophilic substitution reactions of alkyl halides which mostly occur by S_(N)1 and S_(N)2 mechanisms. The rates of S_(N)2 reactions among other things are governed by steric factors while than of S_(N)1 reactions are governed by the stability of intermediate carbocations. chirality has a profound role in undersetanding the mechanism of S_(N)1 and S_(N)2 reactions. whereas S_(N)2 reactions of chiral alkyl halides are accompanied by inversion of configuration, S_(N)1 reactions are characterised by racemisation. Q. In the solvolysis of 3-methyl-3-bromohexane, which of the followin statements is not correct?

    The correct decreasing order of reactivity for a given (R) group in both S_(N^(1)) " and " S_(N^(2)) reaction mechanism is :