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Show how will you synthesie: i. 1-Phe...

Show how will you synthesie:
i. 1-Phenylethanol form a suitable alkene.
ii. Cyclohexylmethanol using an alkyl halide by `SN^(2)` reaction.
iii. Pentan-1-ol using a suitable alkyl halide.

Text Solution

Verified by Experts

(i) Addition of `H_(2)O` to ethenylbenzene (or styrene) in presence of dil. `H_(2)SO_(4)` gives 1-phenylethanol.

(ii) Hydrolysis of cyclohexylmethyl bromide by aqueous NaOH gives cyclohexylmethanol

(iii) Hydrolysis of 1-bromopentane by aqueous `NaOH` gives pentan-1-ol.
`underset("1-Bromopentane")(CH_(3)CH_(2)CH_(2)CH_(2)CH_(2))-Br+NaOH(aq) underset(S_(N)2,"Hydrolysis")overset(Delta)to underset("Pentan-1-ol")(CH_(3)CH_(2)CH_(2)CH_(2)CH_(2))-OH+NaBr`
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PRADEEP-ALCOHOLS, PHENOLS AND ETHERS-NCERT QUESTIONS AND EXERCISES WITH ANSWERS (NCERT EXERCISES)
  1. Write the mechanism of hydration of ethene to yield ethanol.

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  2. You are given benzene, conc. H(2)SO(4), and NaOH. Write the equations ...

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  3. Show how will you synthesie: i. 1-Phenylethanol form a suitable alk...

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  4. Give two reactions that show the acidic nature of phenol. Compare the ...

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  5. Explain why is ortho-nitrophenol more acidic than ortho-methoxyphenol ...

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  6. Explain how does the (---OH) group attached to a carbon of benzene rin...

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  7. Give the equations of the following reactions: i. Oxidation of prop...

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  8. Explain the following with an example: i. Kolbe's reaction ii. R...

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  9. Write the mechanism of acid dehydration of ethanol to yield ethene.

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  10. How are the following conversions carried out ? i. Propene rarr Pro...

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  11. Name the reagents used in the following reactions: i. Oxidation of ...

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  12. Given reason for the higher boiling point of ethanol in comparison to ...

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  13. Give the IUPAC names of the following ethers: (i) C(2)H(5)OCH(2)-und...

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  14. Write the names of reagents and equations for the preparation of follo...

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  15. Illustrate with examples the limitations of Williamson's synthesis for...

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  16. How is 1-propoxyproapane synthesised from propan-1-ol ? Write mechanis...

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  17. Preparation of ethers by acid dehydration of secondary or tetiary alco...

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  18. Write the equation of the reaction of hydrogen iodide with : (i) 1-p...

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  19. Explain the fact that in aryl ethers, (i) the alkoxy group activates t...

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  20. Write the mechanism of the reaction of HI with methoxymethane.

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