Home
Class 11
CHEMISTRY
Assertion Fe rects with HCI produce H(2)...

Assertion Fe rects with HCI produce `H_(2)` gas
Reason Fe is better reducing agent than `H_(2)`

A

If both assertion and reasn are true and reason is the true explanation of the assertion

B

If both assertion and reason are true but reason is not the true explanation of the assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. **Assertion:** Fe reacts with HCl to produce H₂ gas. **Reason:** Fe is a better reducing agent than H₂. ### Step-by-Step Solution: 1. **Understanding the Reaction:** - When iron (Fe) reacts with hydrochloric acid (HCl), it displaces hydrogen from the acid. The reaction can be represented as: \[ \text{Fe} + 2 \text{HCl} \rightarrow \text{FeCl}_2 + \text{H}_2 \uparrow \] - In this reaction, hydrogen gas (H₂) is evolved. 2. **Reactivity Series:** - To determine if Fe can displace H₂ from HCl, we refer to the reactivity series of metals. In the series, metals are arranged in order of their reactivity. - Iron is above hydrogen in the reactivity series, indicating that iron is more reactive than hydrogen. 3. **Conclusion on the Assertion:** - Since iron can displace hydrogen from hydrochloric acid and produce hydrogen gas, the assertion is **true**. 4. **Understanding Reducing Agents:** - A reducing agent is a substance that donates electrons to another substance, causing the other substance to be reduced while itself gets oxidized. - In this case, iron (Fe) can lose electrons to form Fe²⁺ ions: \[ \text{Fe} \rightarrow \text{Fe}^{2+} + 2e^- \] - The oxidation potential of iron (Fe) is +0.44 V, indicating a tendency to oxidize. 5. **Comparing with Hydrogen:** - Hydrogen gas (H₂) can also act as a reducing agent, but its oxidation potential is 0 V (when it loses electrons to form H⁺): \[ \text{H}_2 \rightarrow 2\text{H}^+ + 2e^- \] - Since the oxidation potential of iron is higher than that of hydrogen, iron is a better reducing agent. 6. **Conclusion on the Reason:** - The reason provided is also **true** because iron is indeed a better reducing agent than hydrogen. ### Final Conclusion: Both the assertion and the reason are true, and the reason correctly explains the assertion. ---
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • REDOX REACTIONS

    PRADEEP|Exercise Numerical value type question|1 Videos
  • P-BLOCK ELEMENTS (NITROGEN FAMILY)

    PRADEEP|Exercise Competition focus jee(main and advanced)/ medical entrance special) (VIII. Assertion-Reason Type Questions)|10 Videos
  • S-BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

    PRADEEP|Exercise Assertion -Reason Type Question (Type 2)|19 Videos

Similar Questions

Explore conceptually related problems

Why is H_(2)S a better reducing agent than H_(2)O ?

Why is H_(3)PO_(2) a stronger reducing agent than H_(3PO_(3) ?

Knowledge Check

  • Assertion (A): Sn reacts with HCl to produce H_(2) gas. Reason (R ): Sn is a better reducing agent than H_(2) gas.

    A
    If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.
    B
    If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.
    C
    If `(A)` is correct but `(R )` is incorrect.
    D
    If `(A)` and `(R )` are incorrect.
  • Assertion (A): A reaction between Fe and I_(2) occurs, but a reaction between Fe^(2+) and I^(ө) does not occur. Reason (R ): Fe is a better reducing agent than I^(ө) .

    A
    If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.
    B
    If both `(A)` and `(R )` are correct but `(R )` is not the correct explanation of `(A)`.
    C
    If `(A)` is correct but `(R )` is incorrect.
    D
    If `(A)` and `(R )` are incorrect.
  • Assertion: In queous solution, SO_(2) reacts with H_(2)S liberating sulphur Reason : SO_(2) is an effective reducing agent.

    A
    If both assetion and reson are corect and reason is correct explanation for assertion
    B
    If both assetion and reason are correct but reason is not correct explanation for assertion
    C
    If asertion is correct but reason is incorrect
    D
    If both assetion and reason are incorrect
  • Similar Questions

    Explore conceptually related problems

    H_(2)O_(2) is a better oxidising agents than water.

    Give reason for the following : H_3PO_2 is a stronger reducing agent than H_3PO_3 .

    Which of the following is correct ? (i) Lithium is better reducing agent than sodium (ii) Sodium is better reducing agent than potassium (iii) Rubidium is better reducing agent than sodium (iv) The Rubidium is better reducing agent than lithium

    Assertion (A): In aqueous solution, SO_(2) reacts with H_(2)S liberating sulphur Reason (R ): SO_(2) is an effective reducing agent.

    Assertion. Both C and CO can reduce FeO to Fe but at temperatures above 1073 K it is C which is a better reducing agent than CO while below 1073 K, it is CO which is a better reducing agent than C. Reason. Above 1073 K, Delta _f G^(@) for CO from C is more negative than that of FeO from Fe while below 1073 K, Delta _f G^(@)CO_ 2 from CO is more negative that that of FeO from Fe.