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Assertion Fe rects with HCI produce H(2)...

Assertion Fe rects with HCI produce `H_(2)` gas
Reason Fe is better reducing agent than `H_(2)`

A

If both assertion and reasn are true and reason is the true explanation of the assertion

B

If both assertion and reason are true but reason is not the true explanation of the assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and the reason provided. **Assertion:** Fe reacts with HCl to produce H₂ gas. **Reason:** Fe is a better reducing agent than H₂. ### Step-by-Step Solution: 1. **Understanding the Reaction:** - When iron (Fe) reacts with hydrochloric acid (HCl), it displaces hydrogen from the acid. The reaction can be represented as: \[ \text{Fe} + 2 \text{HCl} \rightarrow \text{FeCl}_2 + \text{H}_2 \uparrow \] - In this reaction, hydrogen gas (H₂) is evolved. 2. **Reactivity Series:** - To determine if Fe can displace H₂ from HCl, we refer to the reactivity series of metals. In the series, metals are arranged in order of their reactivity. - Iron is above hydrogen in the reactivity series, indicating that iron is more reactive than hydrogen. 3. **Conclusion on the Assertion:** - Since iron can displace hydrogen from hydrochloric acid and produce hydrogen gas, the assertion is **true**. 4. **Understanding Reducing Agents:** - A reducing agent is a substance that donates electrons to another substance, causing the other substance to be reduced while itself gets oxidized. - In this case, iron (Fe) can lose electrons to form Fe²⁺ ions: \[ \text{Fe} \rightarrow \text{Fe}^{2+} + 2e^- \] - The oxidation potential of iron (Fe) is +0.44 V, indicating a tendency to oxidize. 5. **Comparing with Hydrogen:** - Hydrogen gas (H₂) can also act as a reducing agent, but its oxidation potential is 0 V (when it loses electrons to form H⁺): \[ \text{H}_2 \rightarrow 2\text{H}^+ + 2e^- \] - Since the oxidation potential of iron is higher than that of hydrogen, iron is a better reducing agent. 6. **Conclusion on the Reason:** - The reason provided is also **true** because iron is indeed a better reducing agent than hydrogen. ### Final Conclusion: Both the assertion and the reason are true, and the reason correctly explains the assertion. ---
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