Home
Class 12
CHEMISTRY
In which delocalisation of positive char...

In which delocalisation of positive charge is possible

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which delocalization of positive charge is possible, we need to understand the concept of charge delocalization and conjugation in organic compounds. Here’s a step-by-step solution: ### Step 1: Understand Delocalization Delocalization refers to the distribution of charge over several atoms rather than being localized on a single atom. This is often seen in resonance structures where charges can shift between different atoms. **Hint:** Look for structures where charge can be shared among multiple atoms. ### Step 2: Identify Conjugation Conjugation occurs when alternating single and multiple bonds allow for the overlap of p-orbitals, which facilitates the delocalization of electrons. For positive charge delocalization, we need to identify systems with conjugated double bonds. **Hint:** Check for alternating double and single bonds in the molecular structure. ### Step 3: Analyze the Structures Examine the given structures to see where the positive charge can shift. - If a positive charge can move to a neighboring atom through resonance (where a double bond can form and a single bond can break), then delocalization is possible. - If the resulting structure after shifting the positive charge is stable, then delocalization is favored. **Hint:** Draw resonance structures to visualize the movement of the positive charge. ### Step 4: Evaluate Stability When the positive charge is delocalized, check if the resulting structure is stable. Stability is often enhanced when the positive charge is adjacent to electronegative atoms or in a conjugated system. **Hint:** Consider the stability of the resulting resonance structures. More stable structures contribute more to the resonance hybrid. ### Step 5: Conclusion After analyzing the structures, conclude which compounds allow for the delocalization of positive charge. The correct answer will be the option where conjugation is possible and the positive charge can be effectively delocalized. **Hint:** Look for the option that explicitly mentions conjugation and stability of the resulting structures. ### Final Answer The correct answer is **Option D**: Delocalization of positive charge is possible due to conjugation in the given compounds.

To determine in which delocalization of positive charge is possible, we need to understand the concept of charge delocalization and conjugation in organic compounds. Here’s a step-by-step solution: ### Step 1: Understand Delocalization Delocalization refers to the distribution of charge over several atoms rather than being localized on a single atom. This is often seen in resonance structures where charges can shift between different atoms. **Hint:** Look for structures where charge can be shared among multiple atoms. ### Step 2: Identify Conjugation ...
Promotional Banner

Topper's Solved these Questions

  • EQUIVALENT CONCEPT & TITRATIONS

    RESONANCE|Exercise Part -IV|22 Videos
  • GASEOUS STATE

    RESONANCE|Exercise Exercise-3|1 Videos

Similar Questions

Explore conceptually related problems

In which of the following carbocations, delocalisation of positive charge is possible :

In which cases delocalisation of charge is possible ?

Assertion: Pyrrolidince (II) is more basic than pyrrole (I) Reason: Protonated pyrrole has delocalisation of positive charge in aromatic ring.

In which of the following , delocalisation of pi- electrons is/are possible?

Resonance is delocalisation of :

Electrons are positively charged.

Identify the positively charged sol

A conductor with a positive charge

Is the atom as a whole positively charged ?

RESONANCE-FUNDAMENTAL CONCEPT-ORGANIC CHEMISTRY(Fundamental Concept )
  1. The chemical system that is non- aromatic is

    Text Solution

    |

  2. Which of the following is the least stable carbanion?

    Text Solution

    |

  3. Arrange stability of the given carbocation in decreasing order :

    Text Solution

    |

  4. Which of the following compound give solvolysis reaction with slowest ...

    Text Solution

    |

  5. Which of the following alkoxides is the most reactive nucleophile?

    Text Solution

    |

  6. Which is the correct matched for the following reactions

    Text Solution

    |

  7. Which is correctly matched

    Text Solution

    |

  8. The correct increasing order of the reactivity of halides for S(N) 1 r...

    Text Solution

    |

  9. Reaction intermediate of EicB reaction is :

    Text Solution

    |

  10. Select false statement from the following ?

    Text Solution

    |

  11. Which of the following is not electrophile ?

    Text Solution

    |

  12. Which statement is incorrect :

    Text Solution

    |

  13. The correct leaving group ability order is :

    Text Solution

    |

  14. CH(3)-CH(2)-O-CH(2)-Clunderset("other")overset(CH(3)MgBr)rarr Which ...

    Text Solution

    |

  15. Which of the following is not a nucleophile ?

    Text Solution

    |

  16. Select the correct option : S(1) : Catechol is less acidic than reso...

    Text Solution

    |

  17. The reaction is : CH(3)CHBr-CH(2)Br+2KOH("alc.")overset(Delta)rarr C...

    Text Solution

    |

  18. For the following (i) I^(-) (ii) Cl^(-) (iii) Br^(-) the increasin...

    Text Solution

    |

  19. Orbital interation ( partial overlapping ) between the sigma bonds of ...

    Text Solution

    |

  20. In which delocalisation of positive charge is possible

    Text Solution

    |