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CH(3)CHO+CH(3)CH(2)CHOoverset(dil. NaOH)...

`CH_(3)CHO+CH_(3)CH_(2)CHOoverset(dil. NaOH)rarr`
The number of product `(s)` in the above reaction is ( are) ( excluding stereoisomers )

A

1

B

2

C

3

D

4

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the reaction between two aldehydes, CH₃CHO (acetaldehyde) and CH₃CH₂CHO (propionaldehyde), in the presence of dilute NaOH. This reaction will lead to aldol condensation. Let's break down the steps: ### Step 1: Identify the Reactants The reactants in the reaction are: - Acetaldehyde (CH₃CHO) - Propionaldehyde (CH₃CH₂CHO) ### Step 2: Understand the Reaction Type The reaction involves aldol condensation, which occurs when aldehydes react in the presence of a base (here, dilute NaOH). This reaction can lead to self-condensation (where one aldehyde reacts with itself) or cross-condensation (where two different aldehydes react). ### Step 3: Self-Condensation of Acetaldehyde 1. **Nucleophile Formation**: In the presence of NaOH, acetaldehyde can form a nucleophile (an enolate ion) by deprotonation. 2. **Nucleophilic Attack**: The nucleophile can attack another molecule of acetaldehyde. 3. **Aldol Product Formation**: This leads to the formation of 3-hydroxybutanal (an aldol). 4. **Dehydration**: The aldol can then dehydrate to form crotonaldehyde (but-2-enal). ### Step 4: Self-Condensation of Propionaldehyde 1. **Nucleophile Formation**: Similarly, propionaldehyde can also form a nucleophile. 2. **Nucleophilic Attack**: The nucleophile can attack another molecule of propionaldehyde. 3. **Aldol Product Formation**: This leads to the formation of 3-hydroxybutanal. 4. **Dehydration**: The aldol can then dehydrate to form 2-methylbut-2-enal. ### Step 5: Cross-Condensation 1. **Nucleophile Formation**: The nucleophile from acetaldehyde can attack propionaldehyde. 2. **Aldol Product Formation**: This leads to the formation of 3-hydroxy-2-methylbutanal. 3. **Dehydration**: The aldol can then dehydrate to form 2-methyl-3-butenal. ### Summary of Products From the above steps, we can summarize the products formed: 1. Crotonaldehyde (from self-condensation of acetaldehyde) 2. 2-Methylbut-2-enal (from self-condensation of propionaldehyde) 3. 2-Methyl-3-butenal (from cross-condensation) ### Final Count of Unique Products We have identified three unique products from the reaction: 1. Crotonaldehyde 2. 2-Methylbut-2-enal 3. 2-Methyl-3-butenal ### Conclusion Thus, the total number of products (excluding stereoisomers) formed in the reaction is **3**.

To solve the problem, we need to analyze the reaction between two aldehydes, CH₃CHO (acetaldehyde) and CH₃CH₂CHO (propionaldehyde), in the presence of dilute NaOH. This reaction will lead to aldol condensation. Let's break down the steps: ### Step 1: Identify the Reactants The reactants in the reaction are: - Acetaldehyde (CH₃CHO) - Propionaldehyde (CH₃CH₂CHO) ### Step 2: Understand the Reaction Type ...
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Knowledge Check

  • CH_(2)=CH_(2)overset(HOCl)rarrAoverset(dil.NaOH)rarrB The final product B formed in the above reaction is

    A
    `HOCH_(2)CH_(2)OH`
    B
    C
    `ClCH_(2)CH_(2)Ona`
    D
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  • CH_(3)CH_(2)CHO overset(NaOH, Delta)underset("aldol")to product A. A is

    A
    `CH_(3)CH_(2)CH=CHCH_(2)CHO`
    B
    `CH_(3)CH_(2)CH=overset(CH_(3))overset(|)C-CHO`
    C
    `CH_(3)CH_(2)underset(OH)underset(|)CH-CH_(2)CH_(2)CHO`
    D
    `CH_(3)CH_(2)underset(OH)underset(|)CH-overset(CH_(3))overset(|)CH-CHO`
  • CH_(3)CHOoverset(HCN)rarr(A) overset(HOH)rarr(B) The product (B) is :

    A
    malonic acid
    B
    lactic acid
    C
    glycolic acid
    D
    malic acid
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