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CH(3)CHO+CH(3)CH(2)CHOoverset(dil. NaOH)...

`CH_(3)CHO+CH_(3)CH_(2)CHOoverset(dil. NaOH)rarr`
The number of product `(s)` in the above reaction is ( are) ( excluding stereoisomers )

A

1

B

2

C

3

D

4

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The correct Answer is:
To solve the problem, we need to analyze the reaction between two aldehydes, CH₃CHO (acetaldehyde) and CH₃CH₂CHO (propionaldehyde), in the presence of dilute NaOH. This reaction will lead to aldol condensation. Let's break down the steps: ### Step 1: Identify the Reactants The reactants in the reaction are: - Acetaldehyde (CH₃CHO) - Propionaldehyde (CH₃CH₂CHO) ### Step 2: Understand the Reaction Type The reaction involves aldol condensation, which occurs when aldehydes react in the presence of a base (here, dilute NaOH). This reaction can lead to self-condensation (where one aldehyde reacts with itself) or cross-condensation (where two different aldehydes react). ### Step 3: Self-Condensation of Acetaldehyde 1. **Nucleophile Formation**: In the presence of NaOH, acetaldehyde can form a nucleophile (an enolate ion) by deprotonation. 2. **Nucleophilic Attack**: The nucleophile can attack another molecule of acetaldehyde. 3. **Aldol Product Formation**: This leads to the formation of 3-hydroxybutanal (an aldol). 4. **Dehydration**: The aldol can then dehydrate to form crotonaldehyde (but-2-enal). ### Step 4: Self-Condensation of Propionaldehyde 1. **Nucleophile Formation**: Similarly, propionaldehyde can also form a nucleophile. 2. **Nucleophilic Attack**: The nucleophile can attack another molecule of propionaldehyde. 3. **Aldol Product Formation**: This leads to the formation of 3-hydroxybutanal. 4. **Dehydration**: The aldol can then dehydrate to form 2-methylbut-2-enal. ### Step 5: Cross-Condensation 1. **Nucleophile Formation**: The nucleophile from acetaldehyde can attack propionaldehyde. 2. **Aldol Product Formation**: This leads to the formation of 3-hydroxy-2-methylbutanal. 3. **Dehydration**: The aldol can then dehydrate to form 2-methyl-3-butenal. ### Summary of Products From the above steps, we can summarize the products formed: 1. Crotonaldehyde (from self-condensation of acetaldehyde) 2. 2-Methylbut-2-enal (from self-condensation of propionaldehyde) 3. 2-Methyl-3-butenal (from cross-condensation) ### Final Count of Unique Products We have identified three unique products from the reaction: 1. Crotonaldehyde 2. 2-Methylbut-2-enal 3. 2-Methyl-3-butenal ### Conclusion Thus, the total number of products (excluding stereoisomers) formed in the reaction is **3**.

To solve the problem, we need to analyze the reaction between two aldehydes, CH₃CHO (acetaldehyde) and CH₃CH₂CHO (propionaldehyde), in the presence of dilute NaOH. This reaction will lead to aldol condensation. Let's break down the steps: ### Step 1: Identify the Reactants The reactants in the reaction are: - Acetaldehyde (CH₃CHO) - Propionaldehyde (CH₃CH₂CHO) ### Step 2: Understand the Reaction Type ...
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RESONANCE-ALDEHYDES, KETONES, CARBOXYLIC ACID-ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)
  1. Observe the following compounds , The correct reactivity order of...

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  2. The compound X can be

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  3. CH(3)CHO+CH(3)CH(2)CHOoverset(dil. NaOH)rarr The number of product ...

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  4. The porduct is :

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  5. 3CH(3)CHOunderset(298K)overset(H^(o+))rarrP Product P is a pleasant ...

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  6. If 3- hexanone is reacted with NaBH(4) followed by hydrolysis with D(2...

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  7. Which of the following compounds is most acidic ?

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  8. The treatment of with concentrated KOH gives

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  9. The compound which readily undergoes decaroxylation is

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  10. The compound which would yield 5- Oxo-2-methylhexanal on reductive ozo...

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  11. Which of the following on heating does not form an anhydride ?

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  12. The productP is :

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  13. {:(CH(3)COOH,H-COOCH(3),CH(3)-CONH(2),CH(3)-CH(2)-CH(2)-OH,),((I),(II)...

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  14. Dry distillation of calcium acetate gives :

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  15. Which one of the following reaction is called Rosenmund reaction ?

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  16. RCOOH after treatment with PCl(5) and KCN is subjected to hydrolysis f...

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  17. In order to get propane gas which of the following should be subjected...

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  18. Acetic acid reacts separately with the following alcohols. The rate ...

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  19. Phenol can be converted into salicyclic acid by :

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  20. A new carbon-carbon bond formation is possible in:

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