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Why the first ionisation energy of carbo...

Why the first ionisation energy of carbon atom is greater than that of boron atom whereas, the reverse is true for the second ionisation energy.

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The correct Answer is:
[Zeff & half filled config.]

`[C = 1s^(2) 2s^(2) 2p^(2)`
`B = 1s^(2) 2s^(2) 2p^(1)`
Left to right atomic size decreases, `IE_(1) uarr` After the removal of `1e^(-), B` acquire fully filled stable s-orbital configuration, therefore `IE_(2)` of `B gt C`
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Knowledge Check

  • The first ionisation energy of first atom is greater than that of second atom, whereas reverse order is true for their second ionisation energy. Which set of elements is not in accordance to above statement ?

    A
    C, B
    B
    P, S
    C
    B, Be
    D
    Mg, Na
  • The first ionisation energy of first atom is greater than that of second atom, whereas reverse order is true for their second ionisation energy. Which set of elements is in accordance to above statement?

    A
    `CgtB`
    B
    `PgtS`
    C
    `BegtB`
    D
    `MggtNa`
  • The first ionisation energy of first atom is greater than that of second atom, whereas reverse order is true for their second ionisation energy. Which set of elements is in accordance to above statement?

    A
    CgtB
    B
    PgtS
    C
    BegtB
    D
    MggtNa
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