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Polar covalent molecules exhibit dipole ...

Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length d for the bond. Unit of dipole moment is Debye. One Debye is equal to `10^(-18)` esu-cm.
Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be used to disinguisd between cis- and trans- isomers, ortho-, meta - and para - forms of a substance, etc.
Among the following, which is a type of non-planar as well as non-polar compound?

A

`H_(2)C=C=CH_(2)`

B

`ClF_(3)`

C

`XeF_(4)`

D

`PF_(3)Cl_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

Allene, `C_(3)H_(4)`, is non-planar as well as non-polar.
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Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. mu of the AX_(4) type of molecule is zero. The geometry of it can be :

Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. mu of the AX_(4) type of molecule is zero. The geometry of it can be :

Knowledge Check

  • Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. Which is a polar molecule?

    A
    `XeF_(4)`
    B
    `BF_(3)`
    C
    `I_(2)Cl_(6)`
    D
    `PCl_(2)F_(3)`
  • Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length d for the bond. Unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu-cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be used to disinguisd between cis- and trans- isomers, ortho-, meta - and para - forms of a substance, etc. Which of the following pair of species have same diple moment value?

    A
    B
    C
    D
    Both (a) and (c)
  • Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation, q and the bond length d for the bond. Unit of dipole moment is Debye. One Debye is equal to 10^(-18) esu-cm. Dipole moment is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be used to disinguisd between cis- and trans- isomers, ortho-, meta - and para - forms of a substance, etc. The dipole moment value of H-X molecule is 1.2 Debye. If the internuclear distance between H-X is 0.8Å then the % ionic character in H-X molecules is :

    A
    `31.25%`
    B
    `50%`
    C
    `14%`
    D
    `25%`
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    Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. Arrange the following compounds in increasing order of dipole moments, toluene (I), o-dichlorobenzene (II), m-dichlorobenzene (III) and p-dichlorobenzene (IV) :

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