Home
Class 12
CHEMISTRY
At 500K, K(p) value for the reaction 2...

At `500K, K_(p)` value for the reaction
`2SO_(2)(g)+O_(2)(g)hArr2SO_(3)(g)` is `2.5xx10^(10)`.
Find the value of `K_(p)` for each of followign reactions at the same temperature.
a. `SO_(2)(g)+1//2O_(2)(g)hArrSO_(3)(g)`
b. `SO_(3)(g)hArrSO_(2)(g)+1//2O_(2)(g)`
c. `3SO_(2)(g)+3//2O_(2)(g)hArr3SO_(3)(g)`

Text Solution

Verified by Experts

1. `2SO_(2)(g)+O_(2)(g)hArr2SO_(3)(g)`
`K_(p)` for the above reaction is `2.5xx10^(10)`
a. `SO_(2)+1/2O_(2)hArrSO_(3)`
The `K_(p)` for this reaction is `sqrt(K_(p))` of the reaction 1
`K_(p)=sqrt(2.5xx10^(10))=1.58xx10^(5)`
b. `SO_(3)(g)hArrSO_(2)(g)+1/2O_(2)(g)`
For this reaction the `K_(p)` is either `1/(sqrt(K_(p)))`
of the reaction 1 or `1/(K_(p))` of the reaction (2).
`K_(p)=1/(sqrt(2.5xx10^(10))` or `1/(1.58xx10^(5))`
`=6.33xx10^(-6)`
c. `3SO_(2)(g)+3/2O_(2)(g)to3SO_(3)`
This reaction is obtained by multiplying the equatio a. with three or by multiplying the equation 1 with 1.5.
So `K_(p)` for this reaction `(K_(p))^(3)` of equaltion (a) `K_(p)=(1.58xx10^(5))^(3)=3.944xx10^(15)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM AND ACIDS-BASES

    VGS PUBLICATION-BRILLIANT|Exercise ADDITIONAL QUESTIONS & ANSWERS|8 Videos
  • CHEMICAL EQUILIBRIUM AND ACIDS-BASES

    VGS PUBLICATION-BRILLIANT|Exercise LONG ANSWER QUESTIONS|16 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    VGS PUBLICATION-BRILLIANT|Exercise LONG ANSWER QUESTIONS|9 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    VGS PUBLICATION-BRILLIANT|Exercise Long Answer Questions|24 Videos

Similar Questions

Explore conceptually related problems

K_(c) for the reaction N_(2)(g)+3H_(2)(g)hArr2N_(3)(g) is 0.5 at 400K find K_(p)

The value of K_(p) for the reaction 2H_(2)S(g) hArr 2H_(2)(g) +S_(2)(g) is 1.2 xx 10^(-2) at 1065^(circ)C . The value of K, for this reaction is

For the reaction CO_((g)) + (1)/(2) O_(2(g)), K_(1)//K_(c) is

VGS PUBLICATION-BRILLIANT-CHEMICAL EQUILIBRIUM AND ACIDS-BASES-NUMERICAL PROBLEMS
  1. For the reactions A+BhArr3C at 25^(@)C, a 3 litre vessel contains 1,2,...

    Text Solution

    |

  2. A mixture of H(2), N(2) and NH(3) with molar concentration 5.0xx10^(-3...

    Text Solution

    |

  3. At 500K, K(p) value for the reaction 2SO(2)(g)+O(2)(g)hArr2SO(3)(g) ...

    Text Solution

    |

  4. K(c) for the reaction N(2)O(g)hArr2NO(2)(g) is 4.63xx10^(-3) at 25^(2)...

    Text Solution

    |

  5. At 27^(@)C, K(p) value for the reversible reaction PCl(5)(g)harrPCl(3)...

    Text Solution

    |

  6. K(c) for the reaction N(2)(g)+3H(2)(g)hArr2N(3)(g) is 0.5 at 400K fi...

    Text Solution

    |

  7. 1 mole of A and 1 mol3 of B are taken in a 5 litre flask, 0.5 mole of...

    Text Solution

    |

  8. For the following reaction PCl(5)(g)hArrPCl(3)(g)+Cl(2)(g)0.4 mole o...

    Text Solution

    |

  9. In an equilibrium A+BhArrC+D,A and B are mixed in a vessel at temperat...

    Text Solution

    |

  10. A mixture of SO(2),SO(3) and O(2) gases are maintained at equilibrium ...

    Text Solution

    |

  11. For A+BhArrC, the equilibrium concentrations of A and B at a temperatu...

    Text Solution

    |

  12. A vessel at 100K contains CO(2) with a pressure of 0.5 atm. Some of th...

    Text Solution

    |

  13. The K(p) values for the reaction H(2)(g)+I(2)(g)hArr2HI(g) at 460^(@...

    Text Solution

    |

  14. 0.5 mol of H(2) and 0.5 mole of I(2) react in 10 litre flast at 448^(...

    Text Solution

    |

  15. How much PCl(5) must be added to a one little vessel at 250^(@)C in or...

    Text Solution

    |

  16. K(p) for the reaction N(2)(g)+3H(2)(g)hArr2NH(3)(g) at 400^(2)C is 1...

    Text Solution

    |

  17. Calculate pH of a. 10^(-3)M HCl b. 10^(-3) MH(2) HO(4) c. 10^(-...

    Text Solution

    |

  18. Calculate the pH for a. 0.001 M NaOH b. 0.01 M Ca(OH)(2) c. 0.00...

    Text Solution

    |

  19. The pH of a solution is 3.6. Calculate H(3)O^(+) ion concentration.

    Text Solution

    |

  20. The pH of a solution is 8.6. Calculate the OH^(-) ion concentration ...

    Text Solution

    |