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A rarr Product and ((dx)/(dt)) = k [A]^(...

`A rarr` Product and `((dx)/(dt)) = k [A]^(2)`. If log `((dx)/(dt))` is plotted against log [A], then graph is of the type:

A

B

C

D

Text Solution

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The correct Answer is:
To solve the given problem step by step, we need to analyze the relationship between the rate of reaction and the concentration of reactant A. ### Step-by-Step Solution: 1. **Understand the Rate Law**: The rate of reaction is given by the equation: \[ \frac{dx}{dt} = k [A]^2 \] where \( \frac{dx}{dt} \) is the rate of reaction, \( k \) is the rate constant, and \( [A] \) is the concentration of reactant A. 2. **Take Logarithms**: To analyze the relationship graphically, we take the logarithm of both sides of the equation: \[ \log\left(\frac{dx}{dt}\right) = \log(k [A]^2) \] 3. **Apply Logarithmic Properties**: Using the properties of logarithms, we can expand the right-hand side: \[ \log\left(\frac{dx}{dt}\right) = \log(k) + \log([A]^2) \] \[ \log\left(\frac{dx}{dt}\right) = \log(k) + 2\log([A]) \] 4. **Rearranging the Equation**: We can rearrange this equation into the form of a straight line \( y = mx + c \): \[ \log\left(\frac{dx}{dt}\right) = 2\log([A]) + \log(k) \] Here, we identify: - \( y = \log\left(\frac{dx}{dt}\right) \) - \( x = \log([A]) \) - The slope \( m = 2 \) - The y-intercept \( c = \log(k) \) 5. **Graph Interpretation**: Since the slope \( m = 2 \) is positive, this indicates that as the concentration of A increases, the rate of reaction also increases. The graph of \( \log\left(\frac{dx}{dt}\right) \) versus \( \log([A]) \) will be a straight line with a positive slope. 6. **Conclusion**: The correct type of graph when plotting \( \log\left(\frac{dx}{dt}\right) \) against \( \log([A]) \) is a straight line with a positive slope. ### Final Answer: The graph is of the type: **Option C** (a straight line with a positive slope).
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