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Reaction between dry ice and methyl magn...

Reaction between dry ice and methyl magnesium bromide gives an addition compound which acidification yields:

A

ethanoic acid

B

propanoic acid

C

ethanal

D

ethanol

Text Solution

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The correct Answer is:
To solve the problem of what product is formed when dry ice reacts with methyl magnesium bromide and is then acidified, we can follow these steps: ### Step 1: Identify the Reactants - Dry ice is solid carbon dioxide (CO₂). - Methyl magnesium bromide is a Grignard reagent, represented as CH₃MgBr. ### Step 2: Understand the Reaction Mechanism - The Grignard reagent (CH₃MgBr) reacts with carbon dioxide (CO₂) to form an addition compound. - In this reaction, the nucleophilic methyl group (CH₃⁻) from the Grignard reagent attacks the electrophilic carbon of carbon dioxide. ### Step 3: Formation of the Addition Compound - When CH₃⁻ attacks CO₂, it forms a carbanion intermediate: \[ \text{CO}_2 + \text{CH}_3^- \rightarrow \text{(CH}_3\text{COO)}^- \] - This intermediate is a carboxylate ion (specifically, the acetate ion). ### Step 4: Acidification of the Addition Compound - Upon acidification (usually with a dilute acid like HCl), the carboxylate ion is protonated: \[ \text{(CH}_3\text{COO)}^- + \text{H}^+ \rightarrow \text{CH}_3\text{COOH} \] - This results in the formation of acetic acid (ethanoic acid). ### Final Product - The final product of the reaction between dry ice and methyl magnesium bromide, followed by acidification, is **acetic acid (ethanoic acid)**. ### Summary of the Reaction 1. Dry ice (CO₂) reacts with methyl magnesium bromide (CH₃MgBr). 2. An addition compound is formed, leading to the carboxylate ion. 3. Acidification of this compound yields acetic acid (CH₃COOH).

To solve the problem of what product is formed when dry ice reacts with methyl magnesium bromide and is then acidified, we can follow these steps: ### Step 1: Identify the Reactants - Dry ice is solid carbon dioxide (CO₂). - Methyl magnesium bromide is a Grignard reagent, represented as CH₃MgBr. ### Step 2: Understand the Reaction Mechanism - The Grignard reagent (CH₃MgBr) reacts with carbon dioxide (CO₂) to form an addition compound. ...
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Knowledge Check

  • Magnesium bromide is a (an) _____ compound.

    A
    metallic
    B
    covalent
    C
    ionic
    D
    dative
  • Reaction between phenyl magnesium bromide and methanol produces

    A
    A mixture of anisole and Mg(OH)Br
    B
    A mixture of benzene and Mg(OME)Br
    C
    A mixture of toluene and Mg(OH)Br
    D
    A mixture of phenol and Mg(Me)Br
  • Dry ice and benzyl magnesium halide produces

    A
    benzoic acid
    B
    phthalic acid
    C
    2-phenylethanoic acid
    D
    2- phenylpropanoic acid
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