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The relation between U, p and V for an i...

The relation between U, p and V for an ideal gas in an adiabatic process is given by relation `U=a+bpV`. Find the value of adiabatic exponent `(gamma)` of this gas.

A

`(b+1)/(b)`

B

`(b+1)/(a)`

C

`(a+1)/(b)`

D

`(a)/(a+b)`

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The correct Answer is:
To find the value of the adiabatic exponent \( \gamma \) for an ideal gas in an adiabatic process given the relation \( U = a + bPV \), we can follow these steps: ### Step 1: Understand the given relation The internal energy \( U \) is expressed as: \[ U = a + bPV \] where \( a \) is a constant, \( b \) is a coefficient, \( P \) is the pressure, and \( V \) is the volume. ### Step 2: Recall the relationship for internal energy in an adiabatic process For an ideal gas, the change in internal energy \( \Delta U \) can be expressed in terms of temperature: \[ \Delta U = nC_V \Delta T \] where \( C_V \) is the molar heat capacity at constant volume, \( n \) is the number of moles, and \( \Delta T \) is the change in temperature. ### Step 3: Relate \( PV \) to temperature Using the ideal gas law, we know: \[ PV = nRT \] where \( R \) is the universal gas constant. ### Step 4: Substitute \( PV \) in the internal energy equation From the ideal gas law, we can express \( T \) as: \[ T = \frac{PV}{nR} \] Substituting this into the expression for internal energy gives: \[ U = a + bPV = a + b \left( nR \frac{T}{n} \right) = a + b \frac{PV}{n} \] ### Step 5: Express \( U \) in terms of \( PV \) We can also express the internal energy in terms of \( PV \): \[ U = \frac{PV}{\gamma - 1} \] This comes from the relation for an ideal gas in an adiabatic process, where \( PV^{\gamma} = \text{constant} \). ### Step 6: Compare the two expressions for internal energy Now we have two expressions for \( U \): 1. \( U = a + bPV \) 2. \( U = \frac{PV}{\gamma - 1} \) Setting these equal gives: \[ a + bPV = \frac{PV}{\gamma - 1} \] ### Step 7: Rearranging the equation Rearranging this equation, we can isolate terms involving \( PV \): \[ bPV = \frac{PV}{\gamma - 1} - a \] Assuming \( PV \neq 0 \), we can divide through by \( PV \): \[ b = \frac{1}{\gamma - 1} - \frac{a}{PV} \] ### Step 8: Solve for \( \gamma \) From the expression \( b = \frac{1}{\gamma - 1} \), we can rearrange to find \( \gamma \): \[ b(\gamma - 1) = 1 \] \[ b\gamma - b = 1 \] \[ b\gamma = 1 + b \] \[ \gamma = \frac{1 + b}{b} \] ### Final Result Thus, the value of the adiabatic exponent \( \gamma \) is: \[ \gamma = 1 + \frac{1}{b} \]
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