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Cu SO4 on mixing with NH3 (1:4 ratio )...

`Cu SO_4 ` on mixing with ` NH_3 (1:4 ratio ) ` does not give test for ` Cu^(2+) ` ions but gives test for ` SO_4^(2-) ` ions why?

Text Solution

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It is because when `NH_3` coordinates to ` Cu^(2+)` ions and it forms the complex ` [Cu(NH_#) _4]SO_4` copper ions are present in coordination sphere , therefore they are non-ionisable whereas `SO_4^(2-) ` ions are counter ions which are ionisable
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