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Dipole moment of cis-2, 3-dichloro-2 but...

Dipole moment of cis-2, 3-dichloro-2 butne is ….. Than the dipole moment of cis1, 2-dichloroethene.

A

more

B

less

C

neither more nor less

D

None of the above

Text Solution

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The correct Answer is:
To determine the dipole moment of cis-2,3-dichloro-2-butene compared to cis-1,2-dichloroethene, we need to analyze the molecular structure and the arrangement of the chlorine atoms in both compounds. ### Step-by-Step Solution: 1. **Identify the Structures**: - **Cis-2,3-dichloro-2-butene** has the following structure: - The butene backbone has a double bond between the second and third carbon atoms. - The two chlorine atoms are attached to the second and third carbon atoms, both on the same side (cis configuration). - **Cis-1,2-dichloroethene** has the following structure: - The ethene backbone has a double bond between the first and second carbon atoms. - The two chlorine atoms are attached to the first and second carbon atoms, also on the same side (cis configuration). 2. **Analyze the Dipole Moments**: - The dipole moment is a vector quantity that depends on the magnitude of the charge and the distance between the charges. - In **cis-2,3-dichloro-2-butene**, the dipole moments of the two C-Cl bonds will add up vectorially because they are oriented in the same direction (due to the cis configuration). - In **cis-1,2-dichloroethene**, the dipole moments of the two C-Cl bonds will also add up, but the overall dipole moment may be affected by the shorter carbon chain and the proximity of the chlorine atoms. 3. **Compare the Dipole Moments**: - The dipole moment of **cis-2,3-dichloro-2-butene** is expected to be larger than that of **cis-1,2-dichloroethene** due to the larger molecular size and the greater distance between the chlorine atoms in the butene structure, which enhances the overall dipole moment. - Therefore, we conclude that the dipole moment of cis-2,3-dichloro-2-butene is greater than that of cis-1,2-dichloroethene. ### Final Answer: The dipole moment of cis-2,3-dichloro-2-butene is greater than the dipole moment of cis-1,2-dichloroethene.

To determine the dipole moment of cis-2,3-dichloro-2-butene compared to cis-1,2-dichloroethene, we need to analyze the molecular structure and the arrangement of the chlorine atoms in both compounds. ### Step-by-Step Solution: 1. **Identify the Structures**: - **Cis-2,3-dichloro-2-butene** has the following structure: - The butene backbone has a double bond between the second and third carbon atoms. - The two chlorine atoms are attached to the second and third carbon atoms, both on the same side (cis configuration). ...
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