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Assertion: Phenol is more reactive than ...

Assertion: Phenol is more reactive than benzene towards electrophilic reactions.
Reason : The +R effect of OH group increases the electron density on benzene nucleus.

A

Both A and R are correct and R is correct explanation of A

B

Both A and R are correct but R is not the correct explanation of A

C

A is correct but R is in correct

D

A is incorrect but R is correct

Text Solution

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The correct Answer is:
A
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A: Phenol is more reactive than toluene towards S_(E) reaction. R: OH group shows +R and +l both effects.

Assertion : Phenol is more reactive than benzene towards electrophilic substitution-reaction Reason : In the case of phenol, the intermediated carbocation is more resonance stabilised

Knowledge Check

  • Assertion. Propene is more reactive than ethene towards electrophilic addition reactions Reason. Hyperconjugation effect of the CH_3 group increases the electron density in the double bond

    A
    If both assertion and reason are true, and reason is the true explanation of the assertion.
    B
    If both assertion and reason are true, but reason is not the true explanation of the assertion.
    C
    If assertion is true, but reason is false.
    D
    If both assertion and reason are false
  • Assertion : Phenol is more reactive than benzene towards electrophilic substitution. Reason : OH group in phenol is ortho and paradirecting in nature.

    A
    If both assertion and reason are correct and reason is correct explanation for assertion.
    B
    If both assertion and reason are correct but reason is not correct explanation for assertion.
    C
    If assertion is correct but reason is incorrect.
    D
    If assertion and reason both are incorrect.
  • Electron density order in the benzene nucleus is

    A
    `I gt II gt III gt IV`
    B
    `I gt III gt II gt IV`
    C
    `IV gt II gt III gt I`
    D
    `I gt IV gt II gt III`
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    Assertion : Chlorobenzene is more reactive than benzene towards the electrophilic substitution reaction. Reason : Resonance destabilizes the carbocation.

    Assertion: Acetanilide is more reactive than aniline towards electrophilic substitution reactions. Reason: The activating effect of NHCOCH_3 is less than that of amino group

    Assertion: Benzaldehyde is more reactive than ethanal towards nucleophilic attact. Reason : The overall effect of- l and +R effect of phenyl group decrease the electron density on the carbon atom of gtC = O group in benzaldehyde.

    STATEMENT-1: Phenol is more reactive than benzene towards electrophilic substitution reaction. and STATEMENT-2: OH group of phenol is electron donating due to resonance.

    Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance stabilised.