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Iron (+II) is one of the most important ...

Iron `(+II)` is one of the most important oxidation states, and salts are called ferrous salts. Most of `Fe(+II)` salts are pale green and contain `[Fe(H_(2)O)_(6)]^(2+)` ion. `Fe(+II)` compounds are easily oxidised by air and so are difficult to obtain pure `Fe^(2+)` form many complexes like `K_(4)[Fe(CN)_(6)]`
Anhydrous `FeCl_(2)` is made by

A

heating Fe with dilute HCl

B

heating Fe with gaseous HCl

C

reacting Fe with conc. HCl

D

heating Fe with `Cl_(2)` gas

Text Solution

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The correct Answer is:
B
Conceptual
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Iron (+II) is one of the most important oxidation states, and salts are called ferrous salts. Most of Fe(+II) salts are pale green and contain [Fe(H_(2)O)_(6)]^(2+) ion. Fe(+II) compounds are easily oxidised by air and so are difficult to obtain pure Fe^(2+) form many complexes like K_(4)[Fe(CN)_(6)] FeSO_(4) is used in brown ring test for nitrates and nitrites. In this test , a freshly prepared FeSO_(4) solution is mixed with solution containing NO_(2)^(-) or NO_(2)^(-) and the conc. H_(2)SO_(4) is run down the side of the test tube. If the mixture gets hot or is shaken. I) the brown colour disappear II) No is evolved III) a yellow solution of Fe_(2)(SO_(4))_(3) is formed

Knowledge Check

  • Iron (+II) is one of the most important oxidation states and salts are called ferrous salts. Most of the Fe(+II) salts are pale green and contain [Fe(H_(2)O)_(6_]^(2+) ion. Fe(+II) compounds are easily oxidised by air and so are difficult to obtain pure Fe^(2+) form many complexes like K_(4)[Fe(CN)_(6)] . Q. Anhydrous FeCl_(2) is made by :

    A
    heating Fe with dilute HCl
    B
    heating Fe with gaseous HCl
    C
    reacting Fe with conc. HCl
    D
    heating Fe with `Cl_(2)` gas

  • Iron (+II) is one of the most important oxidation states, and salts are called ferrous salts. Most of Fe(+II) salts are pale green and contain [Fe(H_(2)O)_(6)]^(2+) ion. Fe(+II) compounds are easily oxidised by air and so are difficult to obtain pure Fe^(2+) form many complexes like K_(4)[Fe(CN)_(6)] K_(3)[Fe(CN)_(6)] is used in the detection of Fe^(2+) ion with which it gives a deep blue colour. This colour is due to the formation of

    A
    `K_(2)Fe[Fe(CN)_(6)]`
    B
    `Fe_(4)[Fe(Cn)_(6)]_(3)`
    C
    `Fe[Fe(CN)_(6)]`
    D
    `Fe_(3)[Fe(CN)_(6)]_(2)`

  • Iron (+II) is one of the most important oxidation states and salts are called ferrous salts. Most of the Fe(+II) salts are pale green and contain [Fe(H_(2)O)_(6_]^(2+) ion. Fe(+II) compounds are easily oxidised by air and so are difficult to obtain pure Fe^(2+) form many complexes like K_(4)[Fe(CN)_(6)]. Q. K_(3)[Fe(CN)_(6)] is used in the detection of Fe^(2+) ion with which it gives a deep blue colour. This colour is due to the formation of :

    A
    `K_(2)Fe[Fe(CN)_(6)]`
    B
    `Fe_(4)[Fe(CN)_(6)]_(3)`
    C
    `Fe[Fe(CN)_(6)]`
    D
    `Fe_(3)[Fe(CN)_(6)]_(2)`

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    Explore conceptually related problems

    Iron (+II) is one of the most important oxidation states and salts are called ferrous salts. Most of the Fe(+II) salts are pale green and contain [Fe(H_(2)O)_(6_]^(2+) ion. Fe(+II) compounds are easily oxidised by air and so are difficult to obtain pure Fe^(2+) form many complexes like K_(4)[Fe(CN)_(6)] . Q. FeSO_(4) is used in brown ring test for nitrates and nitrites. In this test, a freshly prepared FeSO_(4) solution is mixed with solution containing NO_(2)^(-) or NO_(3)^(-) and the conc. H_(2)SO_(4) is run down the side of the test tube. It the mixture gets hot or is shaken. (I) the brown colour disappear (II)NO is evolved (III) a yellow solution in Fe_(2)(SO_(4))_(3) is formed

    H_(2)O_(2) reduces K_(4)Fe(CN)_(6)

    [Fe(H_(2)O)_(6)]^(2+) and [Fe(CN)_(6)]^(4-) differ in

    [Fe(H_(2)O)_(6)]^(2+) and [Fe(CN)_(6)]^(4-) differ in:

    [Fe(H_(2)O)_(6)]^(2+) and [Fe(CN)_(6)]^(4-) differ in :

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