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(i)A blue coloured compound (A) on heati...

(i)A blue coloured compound `(A)` on heating gives two product `(B)` & `( C)`.
(ii)A metal `(D)` is deposited on passing hydrogen through heated `(B)`.
(iii)The solution of `(B)` in `HCl` on treatment with the `[Fe(CN)_(6)]^(4-)` gives a chocolate brown coloured precipitate of compound `(E)`.
(iv)`(C )` turns lime water milky which disappears on continuous passage of `(C )` forming a compound `(F)`.
Identigfy `(A)` to `(F)` and give chemical equations for the reactions at step (i) to (iv).

A

`CuSO_(4)`

B

`CuCO_(3)`

C

`FeSO_(4)`

D

`CrCl_(3)`

Text Solution

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The correct Answer is:
B

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(a). An ore (A) on roasting with sodium carbonate and lime in the presence of air gives two compounds (B) and (C). (b). The solution of (B) in conc. HCl on treatment with potassiu ferroyanide gives a blue colour or precipitate of compound (D).

Knowledge Check

  • A bluish green coloured compound A on heating gives two products B and C . A metal D is deposited on passing H_(2) through heated B. The compound A and B are insolulbe in water. B is black in colour , dissolves in HCl and on treatment with K_(4)[Fe(CN)_(6)] gives a chocolate brown ppt of compound E. C is colourless, odourless gas and turns lime water milkly. The compounds B and C are respectively

    A
    `CuS,SO_(2)`
    B
    `CuO,CO_(2)`
    C
    `FeO,H_(2)S`
    D
    `Cr_(2)O_(3),CO`
  • A bluish green coloured compound A on heating gives two products B and C . A metal D is deposited on passing H_(2) through heated B. The compound A and B are insolulbe in water. B is black in colour , dissolves in HCl and on treatment with K_(4)[Fe(CN)_(6)] gives a chocolate brown ppt of compound E. C is colourless, odourless gas and turns lime water milkly. The compounds D and E are respectively.

    A
    `Cu,Cu_(2)[Fe(CN)_(6)]`
    B
    `Fe,Cu_(2)[Fe(CN)_(6)]`
    C
    `Cr,CuCO_(3)`
    D
    `ZnCuO`