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What is screening effect ?...

What is screening effect ?

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The repulsive force between inner shell electrons and the valence electrons leads to a decreases in the electrostatic attractive forces acting on the valence electrons acts as a shield between the nucleus and the valence electrons
Pauling 's scale :
(i) Electronegativity is the relative tendency of an element present in a covalently bonded molecule to attract the shared pair of electrons towards itself.
(ii) Pauling assigned arbitrary value of electro negativities for hydrogen and fluorine as 2.2 and 4 respectively .
(iii) Based on this the electro negativity values for other elements can be calculated using the following expression .
`(X_(A)-X_(B))=0.182sqrt(E_(AB)-(E_(A A)xxE_(BB))^(1//2))`
Where `E_(AB),E_(aa)andE_(b b)` are the bond dissociation energies of `AB,A_(2)andB_(2)` molecule respectively `X_(A)andX_(B)` are elctro negativity values of A and B.
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Knowledge Check

  • Ionic radii vary in : (1) inversely proportional to the effective nuclear charge ( 2) inversely proportional to the square of the effective nuclear charge. ( 3) direct proportion to the screening effect. (4) direct proportion to the square of screening effect. Choose the correct statements :

    A
    1,2
    B
    1,3
    C
    2,3
    D
    2,4
  • In a given shell the order of screening effect is :

    A
    `s gt p gt d gt f`
    B
    `s gt p gt f gt d`
    C
    ` f gt d gt p gt s`
    D
    ` f gt p gt s gt d`
  • In a given shell the order of screening effect is

    A
    `s gt p gt d gt f`
    B
    `s gt p gt f gt d`
    C
    `f gt d gt p gt s`
    D
    `f gt p gt s gt d`
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