Account for the following: (a) Lower m...

Account for the following:
(a) Lower members of alcohols are soluble in water but higher members are not.
(b) Alcohols cannot be used as solvent for Grignard reagent.

Answer

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Higher alcohols are not soluble in water because of

hydrophilic alkyl group

hydrophobhic alkyl groups

hydrophilic aryl group

hydrophobic aryl groups

Ethyl alcohol cannot be used as a solvent for CH_(3)MgI because

`CH_(3)MgI` reacts with alcohol giving methane

the reaction between them is explosive in natrue

`CH_(3)MgI` is converted to `C_(2)MgI`

alcohol is immicible with `CH_(3)MgI`

Alcohols are soluble in polar solvents like water due to

intermolecular hydogen bonding

intramolecular hydrogen

co-ordinate bonding

ionic bonding