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Components of a non-ideal binary solutio...

Components of a non-ideal binary solution cannot be completely separated by fractional distillation why?

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It forms a azeotrope.
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Components of a non-idea) binary solution cannot be completely separated by fracti.o.nal distillation. Why?

The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids

Knowledge Check

  • Components, A and B, respectively of an ideal binary solution. If X_A represents the mole fraction of component A, the total pressure of the solution will be :

    A
    `p_A + x_A (p_B - p_A)`
    B
    `p_A + x_A (p_A - p_B)`
    C
    `p_B + x_A (p_B-p_A)`
    D
    `p_B + x_A (p_A-p_B)`
  • P_A and P_B are the vapour pressure of pure liquid components A and B respectively of an ideal binary solution. If x_A represents the mole fraction of component A ,the total pressure of the solution will be :

    A
    `P_A+x_A(P_B-P_A)`
    B
    `P_A+x_A(P_A-P_B)`
    C
    `P_B+x_A(P_B-P_A)`
    D
    `P_B+x_A(P_A-P_B)`
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    The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids Solutions which distill without any change in composition or temperature are called

    The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids The azeotropic mixture of water and HCl boils at 108.5^(@)C . This solution is

    The solution which boil at constant temperature like a pure liquid and possess same composition in liquid as well as vapour state are called azeotropes. The components of azetropes cannot be separated by fractional distillation. Only non-ideal solutions form azeotropes. Solutions with negative deviation form maximum boiling azeotrope and the solutions with positive deviation form minimum boiling azeotrope. The boiling point of an azeotrope is never equal to the boiling points of any of the components of the azeotrope. Answer the following question: The azeotropic solutions of two miscible liquids 100 mL of liquid A and 50 mL of liquid B are mixed to form 138 mL solution. It is

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