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For oxidation of iron. 4Fe(s)+3O(2)(g)...

For oxidation of iron.
`4Fe(s)+3O_(2)(g)rarr2Fe_(2)O_(3)(s)`
entropy change is`- 549.4 JK^(-1)mol^(-1)` at 298 K. Inspite of negative entropy change of this reaction, why is the reaction spontaneous?
`(Delta_(r)H^(Ө)` for this reaction is `-1648xx10^(3)J"mol"^(-1)`)

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To determine why the oxidation of iron is spontaneous despite a negative entropy change, we can analyze the thermodynamic principles involved. ### Step-by-Step Solution: 1. **Identify the Given Data:** - The reaction is: \[ 4Fe(s) + 3O_2(g) \rightarrow 2Fe_2O_3(s) ...
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NCERT-THERMODYNAMICS-EXERCISE
  1. For oxidation of iron. 4Fe(s)+3O(2)(g)rarr2Fe(2)O(3)(s) entropy ch...

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  2. Choose the correct answer. A thermodynamic state function is a quantit...

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  3. For the process to occur under adiabatic conditions, the correct condi...

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  4. The enthalpies of the elements in their standard states are arbitraril...

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  5. DeltaU^(Θ) of combustion of methane is -XkJ mol^(-1). The value of Del...

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  6. The enthalpy of combustion of methane, graphite and dihydrogen at 298 ...

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  7. A reaction A +B rarr C+D +q is found to have a positive entropy change...

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  8. In a process, 701 J of heat is absorbed by a system and 394 J of work ...

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  9. The reaction of cyanamide, NH(2)CN(s), with dioxygen was carried out i...

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  10. Calculate the number of kJ of heat necessary to raise the temperature ...

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  11. Calculate the enthalpy change of freezing of 1.0 mol of water at 10^(@...

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  12. Enthalpy of combustion of carbon to CO(2) is -393.5 kJ mol^(-1). Calcu...

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  13. Find the value of Delta(f) H^(@) for the reaction N(2) O(4) (g) + 3 ...

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  14. Given N(2)(g)+3H(2)(g)rarr2NH(3)(g),Delta(r)H^(Ө)= -92.4 kJ mol^(-1...

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  15. Calculate the standard enthalpy of formation of CH(3)OH(l) from the fo...

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  16. Calculate the enthalpy change for the process C Cl(4)(g) rarr C(g)+4...

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  17. For an isolated system, DeltaU=0, what will be Delta S?

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  18. For the reaction at 298 K 2A+B rarr C DeltaH=400 kJ mol^(-1) and D...

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  19. For the reaction 2Cl(g) rarr Cl(2)(g), what are the signs of DeltaH ...

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  20. For the reaction, 2A(g)+B(g) rarr 2D(g) DeltaU^(Θ)=-10.5 kJ and De...

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  21. The equilibrium constant for a reaction is 10. What will be the value ...

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