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Define electronegativity. How does it di...

Define electronegativity. How does it differ from electron gain enthalpy ?

Text Solution

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Electronegativity is the ability of an atom in a chemical compound to attract a bond pair of electron towards itself.
Electronegativity of any given element is not constant. It varies according to the element to which it is bound. It is not a measurable quantity. It is only a relative number.
On the other hand, electron gain enthalpy is hte enthalpy change that takes place when an electron is added to a neutral gaseous atom to form an anion. It can be negative or positive depending upon whether the electron is added or removed. An element has a constant value of the electron gain enthalpy that can be measured experimentally.
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Knowledge Check

  • Second electron gain enthalpy:

    A
    is always negative
    B
    is always positive
    C
    can be positive or negative
    D
    is always zero
  • The correct order of electron gain enthalpy is

    A
    `SgtSegtTegtO`
    B
    `TegtSegtSgtO`
    C
    `OgtSgtSegtTe`
    D
    `SgtOgtSegtTe`
  • The least positive electron gain enthalpy is for

    A
    He
    B
    Ne
    C
    Ar
    D
    Xe
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    The correct order of electron gain enthalpy (in kJ/mole) is