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The stable form of trans-1,4-dimethylcyl...

The stable form of trans-1,4-dimethylcylohexane is represented as:

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
c

First of all, there are two different dimethylcyclohexanes. One has both methyl substituents one the same side of the cyclohexane ring, it is the cis isomer ( cis is Latin for "on this side") The other has two methyl substituents on opposite side of the ring, it is the tran s isomer (trans is Latin for "across" ). cis-,4-dimethylclohexane and trans-1, 4-dimethylcyclohexane are called geometric isomers of cis-1,4-dimethycyclohexane and trans-1, 4-dimethycyclohexane are called geometric isomers of cis-trans stereoisomers-they have the same atoms, and the atoms are linked in the same order, but they differ in the spartial (stereo) arrangement of the atoms.

First we will determine which of the two chair conforms of cis- 1,4-dimethyl-cyclohexane is more stable. One chair conformer has one methyl group in an equatorial position and one methyl group in an axial position. The other chair conformer also has one Therefore, both chair conformers are equally stable.
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Knowledge Check

  • The most stable from trans-1,2-dimethyl cyclohexane is:

    A
    (a) (1e, 2e)
    B
    (b) (1a, 2a)
    C
    (c) (1e, 2a)
    D
    (d) (1a, 2e)
  • The stable conformer (s) of trans -1-4- dimethyl] cyclohexane is/are:

    A
    `1-` axial -`4-` equatorial form
    B
    `1-` axial `-4-` axial form
    C
    `1-` equatorial `-4-` axial from
    D
    `1-` equatorial`-4-` equatorial from
  • The most stable form of cis cyclohexane -1,3-diol is represented as :1

    A
    B
    C
    D
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    How many of the following statements are correct? 1) The most stable conformer of cis-1,3-cyclohexanediol is chair form. 2) Cis-1,3-cyclohexanediol is more stable than trans -1.3-cyclohexanediol. 3) iN Cis 1,3-cyclohexanediol both the OH groups occupy equitorial positions. 4)The most stable conformerf of trans -1,4-cyclohexanediol is chair form. 5) The most stable conformer of Cis-1,4-cyclohexanediol is boat conformer.

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