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Why does benzene undergo electrophilic s...

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

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The correct Answer is:
Due to the rpresence of `6pi` electrons, benzene behaves as a rich source of electroncs thus being easily attached by reagents deficient in electrons.

Benzene is a planar molecule having delocalized electrons above and below the plane of ring. Hence, it is electron-rich. As a result, it is highly attractive to electron deficient species i.e., electrophiles.
Therefore, it undergoes electrophilic substitution reactions very easily. Nucleophiles are electron-rich. Hence, they are repelled by benzene. Hence, benzene undergoes nucleophilic substitutions with difficulty.
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Knowledge Check

  • The ether the undergoes electrophilic substitution reaction is

    A
    `CH_3OC_2H_5`
    B
    `C_6H_5OCH_3`
    C
    `CH_3OCH_3`
    D
    `C_2H_5OC_2H_5`
  • The ether that undergoes electrophilic substitution reactions is

    A
    `CH_(3)OC_(2)H_(5)`
    B
    `C_(6)H_(5)OCH_(3)`
    C
    `CH_(3)OCH_(3)`
    D
    `C_(2)H_(5)OC_(2)H_(5)`
  • The ether that undergoes electrophilic substitution reactions is

    A
    `CH_(3)OC_(2)H_(5)`
    B
    `C_(6)H_(5)OCH_(3)`
    C
    `CH_(3)OCH_(3)`
    D
    `C_(2)H_(5)OC_(2)H_(5)`
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    The ether that undergoes electrophilic substitution reactions is