Home
Class 11
CHEMISTRY
Ethylene reacts with Br(2) to give 1,2-d...

Ethylene reacts with `Br_(2)` to give 1,2-dibromoethane.The anti addition takes place due to the formation of which intermediate?

A

`CH_(2)Br-overset(+)CH_(2)`

B

C

`BrCH-CH^(+)`

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of how ethylene reacts with bromine to form 1,2-dibromoethane through anti-addition, we can break down the process into several steps: ### Step 1: Understanding the Reactants Ethylene (C2H4) has a double bond between the two carbon atoms. The structure can be represented as: \[ \text{CH}_2= \text{CH}_2 \] ### Step 2: Reaction with Bromine When ethylene reacts with bromine (Br2), the double bond acts as a nucleophile and attacks one of the bromine atoms. This leads to the formation of a cyclic bromonium ion intermediate. ### Step 3: Formation of the Bromonium Ion As the double bond attacks one of the bromine atoms, the bond between the bromine atoms breaks. This results in the formation of a bromonium ion, which is a three-membered cyclic structure where one bromine atom is positively charged and is bonded to both carbon atoms of the ethylene: \[ \text{Br}^+ \text{C}_2\text{H}_4 \] ### Step 4: Nucleophilic Attack The negatively charged bromide ion (Br-) that was released during the formation of the bromonium ion can now attack the more substituted carbon atom of the bromonium ion. This attack occurs from the opposite side of the bromonium ion, leading to anti-addition. ### Step 5: Final Product Formation This results in the formation of 1,2-dibromoethane (CH2Br-CH2Br), where the two bromine atoms are added to opposite sides of the original double bond: \[ \text{CH}_2\text{Br}-\text{CH}_2\text{Br} \] ### Conclusion The anti-addition occurs due to the formation of the bromonium ion intermediate, which allows the bromide ion to attack from the opposite side, leading to the final product. ### Answer The anti-addition takes place due to the formation of the bromonium ion intermediate. ---

To solve the question of how ethylene reacts with bromine to form 1,2-dibromoethane through anti-addition, we can break down the process into several steps: ### Step 1: Understanding the Reactants Ethylene (C2H4) has a double bond between the two carbon atoms. The structure can be represented as: \[ \text{CH}_2= \text{CH}_2 \] ### Step 2: Reaction with Bromine When ethylene reacts with bromine (Br2), the double bond acts as a nucleophile and attacks one of the bromine atoms. This leads to the formation of a cyclic bromonium ion intermediate. ...
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBONS (ALKANE, ALKENE and ALKYNE)

    HIMANSHU PANDEY|Exercise Level 2 (Q.1 To Q.25)|24 Videos
  • HYDROCARBONS (ALKANE, ALKENE and ALKYNE)

    HIMANSHU PANDEY|Exercise Level 2 (Q.26 To Q.50)|25 Videos
  • HYDROCARBONS (ALKANE, ALKENE and ALKYNE)

    HIMANSHU PANDEY|Exercise Subjective Type Problems|10 Videos

Similar Questions

Explore conceptually related problems

Propene reacts with Br_(2) to give 1,2-dibromopropane.The anti addition takes place due to the formation of intermediate:

Ethylene reacts with S_(2)Cl_(2) to give

Ethylene reacts with Br_(2) to give 1,2 -dibromoethane. The reaction proceeds through the formation of the intermediate

Phenol reacts with Br_(2) in H_(2)O to give

Ethylene reacts with Br_(2) in methanol to yeild

Anti markwnikoff's addition takes place in the reactions

Anti markovnikov's addition takes place in the presence of

Anti Markownikov addition takes place in which of the following reactions

1,2- dibromoethane when heated with alcohilic potash gives

HIMANSHU PANDEY-HYDROCARBONS (ALKANE, ALKENE and ALKYNE)-Level 1 (Q.26 To Q.50)
  1. Which of the following reaction will lead to creation of two chiral ce...

    Text Solution

    |

  2. The reaction of ethylene with Br(2) in water in the presence of NaCI g...

    Text Solution

    |

  3. A hydrocarbon C(8)H(14) consumes only one mole of H(2) on catalytic hy...

    Text Solution

    |

  4. Dipole moment of which compound will be maximum ?

    Text Solution

    |

  5. Correct order of reactivity towards electrophilic additon reactions is...

    Text Solution

    |

  6. Rank the following in order of statbility (lower to highest) (I)

    Text Solution

    |

  7. The following two compounds are:

    Text Solution

    |

  8. Compound (A) on oxidation withg OsO(4)//NaIO(4) gives hexanedial.Struc...

    Text Solution

    |

  9. A and B are:

    Text Solution

    |

  10. Index of unsaturation (H-deficiency)ofC(8)H(10) is…and if it has a six...

    Text Solution

    |

  11. Which of the following yields But-2 ene on dehydration with conc.H(2)S...

    Text Solution

    |

  12. An alcohol (a) on dehydration gives (B), which on ozonolysis gives ace...

    Text Solution

    |

  13. which of the following compound undergoes dehydrochlorination most eas...

    Text Solution

    |

  14. Which is most easily dehydrohalogenated ?

    Text Solution

    |

  15. Cyclohexene on reaction with OsO(4) followed by reaction with NaHSO(3)...

    Text Solution

    |

  16. Among the following incorrect sttement (s) is//are:

    Text Solution

    |

  17. Ethylene reacts with Br(2) to give 1,2-dibromoethane.The anti addition...

    Text Solution

    |

  18. Which of the following reactions will result in the formation of a chi...

    Text Solution

    |

  19. One mole of a hydrocarbon on ozonolysis yields one mole of glyoxal and...

    Text Solution

    |

  20. A hydrocarbon (A) on chlorinatio gives (B) ,which on reacting with alc...

    Text Solution

    |