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Calculate gamma ( ratio of C(p) & C(v) ...

Calculate `gamma` ( ratio of `C_(p) ` & `C_(v)` ) for
Triatomic nonlinear gas at low temperature.

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To calculate the ratio of specific heats \( \gamma \) (gamma) for a triatomic nonlinear gas at low temperature, we will follow these steps: ### Step 1: Identify Degrees of Freedom For a triatomic nonlinear gas, we need to consider the translational and rotational degrees of freedom. At low temperatures, we will not consider vibrational degrees of freedom. - **Translational Degrees of Freedom (f_t)**: A molecule can move in three dimensions (x, y, z), which gives it 3 translational degrees of freedom. - **Rotational Degrees of Freedom (f_r)**: A nonlinear molecule can rotate about three axes, which gives it 3 rotational degrees of freedom. ### Step 2: Calculate \( C_v \) The molar heat capacity at constant volume \( C_v \) can be calculated using the formula: \[ C_v = \left( \frac{f_t}{2} + \frac{f_r}{2} \right) R \] Substituting the values: \[ C_v = \left( \frac{3}{2} + \frac{3}{2} \right) R = 3R \] ### Step 3: Calculate \( C_p \) The molar heat capacity at constant pressure \( C_p \) is related to \( C_v \) by the equation: \[ C_p = C_v + R \] Substituting the value of \( C_v \): \[ C_p = 3R + R = 4R \] ### Step 4: Calculate \( \gamma \) Now, we can calculate \( \gamma \) using the formula: \[ \gamma = \frac{C_p}{C_v} \] Substituting the values of \( C_p \) and \( C_v \): \[ \gamma = \frac{4R}{3R} = \frac{4}{3} \approx 1.33 \] ### Final Answer Thus, the value of \( \gamma \) for a triatomic nonlinear gas at low temperature is approximately \( 1.33 \). ---
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Calculate gamma ( ratio of C_(p) & C_(v) ) for Triatomic linear gas at high temperature , assume that the contribution of vibrational degree of freedom is 50% .

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Knowledge Check

  • Calculate gamma (ratio of C_(p) and C_(v) ) for triatomic linear gas at high temperature. Assume that the contribution of vibrational degree of freedom is 75% :

    A
    1.222
    B
    1.121
    C
    1.18
    D
    1.33
  • The ratio gamma((C_(P))/(C_(V))) for iner gases is

    A
    1.33
    B
    1.66
    C
    2.13
    D
    1.99
  • The molar specific heat of an ideal gas at constant pressure and constant volume is C_(p) and C_(v) respectively. If R is the universal gas constant and the ratio of C_(p) to C_(v) is gamma , then C_(v) .

    A
    `(1-gamma)/(1+gamma)`
    B
    `(1+gamma)/(1-gamma)`
    C
    `(gamma-1)/(R)`
    D
    `(R)/(gamma-1)`
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