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The half-life of a zero order reaction i...

The half-life of a zero order reaction is x second. If the reaction takes `t_(1)` second to complete, calculate `t_(1)` in terms of x.

Text Solution

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The integrated rate equation of a zero order reaction is : `[A]=[A]_(0)-kt,` where `[A]_(0)` = initial concentration of the reactant [A] = concentration of the reactant after time't' (from the start of the reaction) and k = rate constant.
(1) when, `t=x,[A]=([A]_(0))/(2)`
`therefore([A]_(0))/(2)=[A]_(0)-kxthereforex=([A]_(0))/(2k) " " ...[1]`
If the reaction takes time `t_(1)` to reach completion,
as this time , `[A]=0and 0 = [A]_(0)-kt_(1)`
or, `t_(1)=([A]_(0))/(k) " "..[2]`
From equations [1] and [2] we get,
`x=(1)/(2)([A]_(0))/(k)=(1)/(2)t_(1) therefore t_(1)=2xx"x"`
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Knowledge Check

  • The half life period for a first order reaction is .......

    A
    independent of concentration
    B
    proportional to concentration
    C
    inversely proportional to concentration
    D
    inversely proportional to the square of the concentration
  • The unit of second order reaction rate constant is

    A
    `L^-1 mol s^-1`
    B
    `L^2 mol^-2 s^-1`
    C
    `L mol^-1 s^-1`
    D
    `s^-1`
  • Units of specific reaction rate for second order reaction is

    A
    `s^-1`
    B
    `mol L^-1 s^-1`
    C
    `L^2 mol^-2 s^-1`
    D
    `L mol^-1 s^-1`
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