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'Molecularity' applies only to elementa...

'Molecularity' applies only to elementary reactions However 'order' applies to both elementary as well as complex reactions. Explain.

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An elementary reaction is a single molecular event in which reactant molecules collide simultaneously to form Product molecules. So, we can determine the number of reacting species or molecularity of an elementary reaction from the balanced chemical equation of the reaction. A complex reaction involves a sequence of elementary steps each of which has its own molecularity. Hence, it is meaningless to talk about the overall molecularity of a reaction. On the other hand, reaction order is purely an experimental quality, which expresses how the reaction-rate affected due to change in concentration of the reactants. So, the term 'order' is equally important for both elementary and complex reactions.
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Knowledge Check

  • The unit of rate constant of elementary reaction depends upon the

    A
    temperature of the reaction
    B
    concentration of reactant
    C
    activation energy of the reaction
    D
    molecularity of the reaction
  • The rate of the elementary reaction 2NO +O_2 to 2NO_2 when the volume of reaction vessel is doubled,

    A
    will increase eight times of initial rate
    B
    reduce to one eighth of its initial rate
    C
    will grow four times of its initial rate
    D
    reduce to one fourth of its initial rate
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    Order and molecularity are the same for what type of reactions?

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