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Sulphur is paramagnetic in the vapour st...

Sulphur is paramagnetic in the vapour state-why?

Text Solution

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In the vapour state ( -1000 K) , sulphur mainly exists as `S_(2)` molecules. From the molecular orbital electronic configuration of `S_(2)` molecule, it becomes evident that the molecule (like `O_(2)` ) has two unpaired electrons in the antibonding `pi` -molecular orbitals. Hence, sulphur is paramagnetic in nature in the vapour state.
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Knowledge Check

  • Paramagnetic species are-

    A
    `O_(2)^(+)`
    B
    `O_(2)^(-)`
    C
    `N_(2)^(+)`
    D
    `N_(2)^(-)`
  • Two liquids having vapour pressures p_1^0 and p_2^0 in pure state in the ratio of 2:1 are mixed in the motar ratio of 1:2. The ratio of their moles in the vapour state would be:

    A
    1:1
    B
    1:2
    C
    2:1
    D
    3:2
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