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Explain the principle of removal of rust...

Explain the principle of removal of rust stains from clothes using oxalic acid solution.

Text Solution

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Rust is `Fe_(2)O_(3).` Ferric `(Fe^(3+)` ion reacts with oxalate `(C_(2)O_(4)^(2-))` ion to form a complex ion that is soluble in water.
`H_(2)C_(2)O_(4)" [oxalic acid]" hArr 2H^(+)+C_(2)O_(4)^(2-)" [oxalate ion]"`
`Fe^(3+)+3C_(2)O_(4)^(2-) rarr underset(" Complex ion (soluble)")([Fe(C_(2)O_(4))_(3)]^(3-)`
The clothes are first treated with oxalic acid solution and then rinsed well with water 10 remove the rust stains.
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Knowledge Check

  • Calculate the normality of a solution containing 3.15g of hydrated oxalic acid dissolved in 300 ml of the solution

    A
    8.5 N
    B
    4.6 N
    C
    0.5N
    D
    0.2 N
  • 25 cm^3 of oxalic acid completely neutralised 0. 064g of sodium hydroxide. Molarity of the oxalic acid solution is

    A
    0.064
    B
    0.045
    C
    0.015
    D
    0.032
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