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Chlorobenzene gives aniline with-...

Chlorobenzene gives aniline with-

A

`NH_(3)//Cu_(2)O`

B

`NH_(3)//H_(2)SO_(4)`

C

`NaNH_(2)`

D

None of these

Text Solution

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The correct Answer is:
A, C
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Write the structure of the product when chlorobenzene is treated with methyl chloride in the presence of sodium metal and dry ether.

Chlorobenzene on mononitration with mixed acid gives mainly a mixture of two products.Write an arrow head equation of the reaction and explain why these two compounds are mainly formed.

Knowledge Check

  • Which one of the following compunds is expected to be formed when chlorobenzene is treated with chloral in the presence of conc. H_(2)SO_(4) -

    A
    gammexane
    B
    hexachloroethane
    C
    freon
    D
    DDt

  • Chlorobenzene reacts with which one of the following compounds to form aniline-

    A
    `NH_(3)//Cu_(2)O`
    B
    `NH_(3)//H_(2)SO_(4)`
    C
    `NaNH_(2), NH_(3)(l)`
    D
    None of these

  • Chlorobenzene on treatment with sodium in dry ether gives diphenyl. The name of the reaction is

    A
    Fitting reaction
    B
    Wurtz-Fittig reaction
    C
    Sandmeyer reaction
    D
    Wurtz reaction

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    Explore conceptually related problems

    Chlorobenzene is converted into phenol through the formation of _________(intermediate)

    Explain why chlorobenzene is less reactive towards nucleophilic substitution (SN_1) and (SN_2) reaction.

    Give reasons- (ii) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.

    Give reasons- (i) C-Cl bond length in chlorobenzene is shorter than C-Cl bond length in CH_(3)-Cl .

    Assertion (A) : It is difficult to replace chlorine by -OH in chlorobenzene in comparison to that in chlorobenzene in comaparision to that in chloroethane. Reason (R) : Chlorine-carbon (C-Cl) bond in chlorobenzene has partial double bond character due to resonance.

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