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In Be(2) the bond order is...

In `Be_(2)` the bond order is

A

one

B

zero

C

two

D

one-half

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To determine the bond order of the beryllium molecule \( \text{Be}_2 \), we will follow these steps: ### Step 1: Understand the Molecular Orbital Configuration Beryllium (Be) has an atomic number of 4, which means each beryllium atom has 4 electrons. In \( \text{Be}_2 \), there are a total of 8 electrons (4 from each Be atom). ### Step 2: Fill the Molecular Orbitals The molecular orbital (MO) configuration for \( \text{Be}_2 \) is as follows: - The order of filling the molecular orbitals for diatomic molecules like \( \text{Be}_2 \) is: - \( \sigma_{1s} \) - \( \sigma_{1s}^* \) (anti-bonding) - \( \sigma_{2s} \) - \( \sigma_{2s}^* \) (anti-bonding) - \( \sigma_{2p_z} \) - \( \pi_{2p_x} = \pi_{2p_y} \) - \( \pi_{2p_x}^* = \pi_{2p_y}^* \) (anti-bonding) - \( \sigma_{2p_z}^* \) (anti-bonding) For \( \text{Be}_2 \), the 8 electrons will fill the molecular orbitals as follows: - \( \sigma_{1s}^2 \) (2 electrons) - \( \sigma_{1s}^* \) (0 electrons) - \( \sigma_{2s}^2 \) (2 electrons) - \( \sigma_{2s}^* \) (0 electrons) - \( \sigma_{2p_z}^0 \) (0 electrons) - \( \pi_{2p_x}^0 \) (0 electrons) - \( \pi_{2p_y}^0 \) (0 electrons) ### Step 3: Count the Electrons in Bonding and Anti-bonding Orbitals - **Bonding Molecular Orbitals (BMOs)**: - \( \sigma_{1s} \): 2 electrons - \( \sigma_{2s} \): 2 electrons - Total bonding electrons = 2 + 2 = 4 - **Anti-bonding Molecular Orbitals (ABMOs)**: - \( \sigma_{1s}^* \): 0 electrons - \( \sigma_{2s}^* \): 0 electrons - Total anti-bonding electrons = 0 + 0 = 0 ### Step 4: Calculate the Bond Order The bond order is calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of bonding electrons} - \text{Number of anti-bonding electrons})}{2} \] Substituting the values we found: \[ \text{Bond Order} = \frac{(4 - 0)}{2} = \frac{4}{2} = 2 \] ### Conclusion The bond order of \( \text{Be}_2 \) is **0**.

To determine the bond order of the beryllium molecule \( \text{Be}_2 \), we will follow these steps: ### Step 1: Understand the Molecular Orbital Configuration Beryllium (Be) has an atomic number of 4, which means each beryllium atom has 4 electrons. In \( \text{Be}_2 \), there are a total of 8 electrons (4 from each Be atom). ### Step 2: Fill the Molecular Orbitals The molecular orbital (MO) configuration for \( \text{Be}_2 \) is as follows: - The order of filling the molecular orbitals for diatomic molecules like \( \text{Be}_2 \) is: ...
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Knowledge Check

  • The bond order of N_2 is

    A
    1
    B
    2
    C
    3
    D
    None of these
  • The bond order of O_2 is

    A
    1
    B
    2
    C
    3
    D
    None of these
  • Assertion . Bond order can assume any value including zero. Reason. Higher the bond order, shorter is the bond length and greater is the bond energy.

    A
    If both assertion and reason are correct, and reason is the correct explanation of the assertion.
    B
    If both assertion and reason are correct , but reason is not the correct explanation of the assertion.
    C
    If assertion is correct, but reason is incorrect .
    D
    If both assertion and reason are incorrect.
  • Similar Questions

    Explore conceptually related problems

    How does molecular orbital theory account for the following? (a) Bond order of N_(2) is greater than N_(2)^(+) but the bond order of O_(2) is less than that of O_(2)^(+) . (b ) Be_(2) does not exist.

    Define bond order. Calculate the bond order in N_(2) and O_(2) molecules.

    Find the bond order of Be_2

    Assertion : Bond order can assume any value number including zero. Reason :Higher the bond order ,shorter is bond length and greater is bond energy.

    Assertion : F_(2)and O_(2)^(2-) have bond order 1 while N_(2),CO and NO^(+) have bond order 3. Reason : Higher the bond order, higher is the stability of the molecule.