Home
Class 12
CHEMISTRY
DeltaE=0 for which process...

`DeltaE=0` for which process

A

Cyclic process

B

Isothermal expansion

C

Isochoric process

D

Adiabatic process

Text Solution

AI Generated Solution

The correct Answer is:
To determine for which process the change in internal energy (ΔE or ΔU) is zero, we will analyze the four types of thermodynamic processes: cyclic, isothermal, isochoric, and adiabatic. ### Step-by-Step Solution: 1. **Understanding ΔU**: - ΔU represents the change in internal energy of a system. It is a state function, meaning it depends only on the initial and final states of the system, not on the path taken. 2. **Cyclic Process**: - In a cyclic process, the system returns to its initial state after completing a cycle. Therefore, the initial and final states are the same. - Since ΔU depends only on these states, for a cyclic process, ΔU = U_final - U_initial = 0. - **Conclusion**: ΔU = 0 for cyclic processes. 3. **Isothermal Process**: - In an isothermal process, the temperature remains constant (ΔT = 0). - The change in internal energy for an ideal gas is given by ΔU = Cv * ΔT, where Cv is the heat capacity at constant volume. - Since ΔT = 0, it follows that ΔU = Cv * 0 = 0. - **Conclusion**: ΔU = 0 for isothermal processes. 4. **Isochoric Process**: - In an isochoric process, the volume remains constant (ΔV = 0). - The work done (W) is given by W = -PΔV, which equals 0 since ΔV = 0. - According to the first law of thermodynamics, ΔU = Q + W. Since W = 0, ΔU = Q, which is not necessarily zero (it depends on the heat added or removed). - **Conclusion**: ΔU ≠ 0 for isochoric processes. 5. **Adiabatic Process**: - In an adiabatic process, there is no heat exchange with the surroundings (Q = 0). - Using the first law of thermodynamics, ΔU = Q + W = 0 + W = W. Thus, ΔU is equal to the work done, which is not necessarily zero. - **Conclusion**: ΔU ≠ 0 for adiabatic processes. ### Final Answer: The change in internal energy (ΔU) is zero for: - **Cyclic Process** (Option 1) - **Isothermal Process** (Option 2)

To determine for which process the change in internal energy (ΔE or ΔU) is zero, we will analyze the four types of thermodynamic processes: cyclic, isothermal, isochoric, and adiabatic. ### Step-by-Step Solution: 1. **Understanding ΔU**: - ΔU represents the change in internal energy of a system. It is a state function, meaning it depends only on the initial and final states of the system, not on the path taken. 2. **Cyclic Process**: ...
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

How many of the following statement(s) is/are true for free expansion of ideal gas in an insulated container ? 1. It is a Reversible process. 2. Delta H=0 , for this process. 3. Delta E=0 , for this process. 4. Delta(PV)=0 5. Delta T = 0 , for this process. 6. Delta S_("surrounding")=0 , for this process. 7. Delta S_("system")=0 , for this process. 8. Delta S_("total") = 0 , for this process.

Predict the sign of q, w and Delta U for given process. Hence , find number of process for which at least one of q,w, DeltaU,DeltaH are zero.

Knowledge Check

  • In case of an ideal gas undergoing transformation where Delta T = 0 for the process, its internal energy ______.

    A
    increases as the pressure increases
    B
    decreases as the volume decreases
    C
    decreases as the pressure decreases
    D
    remains fixed
  • River Delta Formation is a result of which process?

    A
    Erosion
    B
    Evaporation
    C
    Sedimentation
    D
    Deposition
  • For a certain process, DeltaH =280 kJ and DeltaS=140 J K^(-1) "mol"^(-1) . What is the minimum temperature at which the process will be spontaneous?

    A
    2000 K
    B
    1200 K
    C
    1400 K
    D
    1420 K
  • Similar Questions

    Explore conceptually related problems

    A process has Delta H = 8 K J mol^(-1) " and " Delta S = 80JK^(-1) mol^(-1) The temperature at which the process will be in equilibrium is ____________ K.

    A process has Delta H= 200 J mol^(-1) and DeltaS=40" JK"^(-1)mol^(-1) . Out of the values given below, choose the minimum temperature above which the process will be spontaneous :

    A process has DeltaH=200Jmol^(-1) and DeltaS=40JK^(-1)mol^(-1) . The minimum temperature above which the process will be spontaneous is ___________K.

    The Delta G in the process of melting of Ice at -15^(@) C is

    DeltaU=0 in a noncylic process of an ideal gas. The process