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For the following Assertion and Reason t...

For the following Assertion and Reason the correct option is:
Assertion :The pH of water increases with increase in temperature
Reason : The dissociation of water into `H^(+)` and `OH^(-)` is an exothermic reaction

A

Assertion is not true, but reason is true

B

Both assertion and reason are true, but the reason is not the correct explanation for the

C

Both assertion and reason are false

D

Both assertion and reason are true, and the reason the correct explanation for the assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "The pH of water increases with an increase in temperature." - Normally, pure water has a pH of 7 at 25°C. As the temperature increases, the dissociation of water into hydrogen ions (H⁺) and hydroxide ions (OH⁻) occurs more readily. 2. **Effect of Temperature on Water Dissociation**: - The dissociation of water can be represented by the equation: \[ H_2O \rightleftharpoons H^+ + OH^- \] - As temperature increases, the equilibrium shifts to the right, leading to an increase in the concentration of H⁺ ions. 3. **Calculating pH**: - pH is calculated using the formula: \[ \text{pH} = -\log[H^+] \] - If the concentration of H⁺ ions increases, the pH value will actually decrease (not increase). 4. **Understanding the Reason**: - The reason states that "The dissociation of water into H⁺ and OH⁻ is an exothermic reaction." - This statement is incorrect. The dissociation of water is an endothermic process, meaning it absorbs heat. When heat is added, the reaction shifts to produce more H⁺ and OH⁻ ions. 5. **Conclusion**: - The assertion is false because the pH of water actually decreases with an increase in temperature (it becomes more acidic). - The reason is also false because the dissociation of water is an endothermic reaction, not exothermic. ### Final Answer: Both the assertion and the reason are false.

To solve the question regarding the assertion and reason provided, we will analyze both statements step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "The pH of water increases with an increase in temperature." - Normally, pure water has a pH of 7 at 25°C. As the temperature increases, the dissociation of water into hydrogen ions (H⁺) and hydroxide ions (OH⁻) occurs more readily. ...
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These questions consist two statements each, printed as Assertion and reason, while answering these question you are required to choose any one of the following four responsis: (a) If both the assertion and reason are true and reason is a true explanation of the assertion. (b) If both the assertion and reason are true but the reason is not the correct explanation of assertion. (c ) If the assertion is true but reason is false. (d) If both the assertion and reason are false. Q. Assertion: Surface tension decreases with increase in temperature. Reason: On increasing temperature kinetic energy increases and intermolecular forces decreases.

Assertion: pH of water increases on increasing temperature. Reason: H_(2)O rarr H^(+) + OH^(-) is an exothermic process.

Knowledge Check

  • Assertion: pH of water increases with increases in temperature . Reason : With increase in temperature, K_w of water increases.

    A
    Assertion and reason both are correct statements and Reason is correct explanation for assertion.
    B
    Assertion and reason both are correct statement but reason is not correct explanation for assertion
    C
    Assertion is correct statement but reason is wrong statement.
    D
    Assertion is wrong statement but reason is correct statement
  • Assertion (A): pH of water increases with an increase in temperature. Reason (R) : K_(w) or water increases with increase in temperature.

    A
    If both (A) and (R) are correc, and (R) is the correct explanation of (A).
    B
    If both (A) and (R) are correct but (R) is not the correct explanation of (A).
    C
    If (A) is correct, but (R) is incorrect.
    D
    If (A) is incorrect, but (R) is correct.
  • With increases in temperature pH of pure water

    A
    increases
    B
    Decreases
    C
    Remains constant
    D
    May increase or decrease
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    Statement-1. pH of water increases with increase in temperature. Statement-2. K_(w) of water increases with increase in temperature.

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