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The oxidation state of S-atoms in Caro'...

The oxidation state of S-atoms in Caro's and Marshall's acids are:

A

`+6,+6`

B

`+6,+4`

C

`+6,-6`

D

`+4,+6`

Text Solution

Verified by Experts

The correct Answer is:
A

Caro's acid `=H_(2)SO_(5)`
Marshell's acid `=H_(2)S_(2)O_(3)`
The oxidation state in both the acids is +6 each because oxidation state cannot be greater than the number of valence electrons.
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Knowledge Check

  • The oxidation state of O-atom is +2 in

    A
    `OF_2`
    B
    `O_2F_2`
    C
    `H_2O`
    D
    `H_2O_2`
  • Caro's and Marshall'a acid does not react with

    A
    S
    B
    `KMnO_4`
    C
    `KI`
    D
    `H_2 O`
  • The oxidation state of S in Caro's acid ( permono sulphuric acid ) H_(2)SO_(5) is "_____________" .

    A
    `+8`
    B
    `+6`
    C
    `+5`
    D
    `+4`
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