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Hybridization in phosphorus in PCl5 in s...

Hybridization in phosphorus in `PCl_5` in solid state

A

`sp^3`

B

`sp^3d^2`

C

`sp^3d`

D

Both 1 and 2

Text Solution

Verified by Experts

The correct Answer is:
D
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Solid State L5

Asserartion: PCl_(5) is covalent in gaseous and liquide states but ionic in solid state. Reason: PCl_(5) in solid state consits of tetrahhedral PCl_(4)^(+) cation and octahedral PCl_(6)^(-) anion.

Knowledge Check

  • The hybridization of phosphorus in POCl_(3) is the same

    A
    P in ` PCl_(3)`
    B
    S in ` SF_(4)`
    C
    `Cl " in" ClF_(3)`
    D
    B in ` BCl_(3)`

  • PCl_5 in solid state exists as.

    A
    `PCl_5`
    B
    `PCl_4^(oplus)`
    C
    `PCl_6`
    D
    `PCl_4 ^(oplus) PCl_6^(Ө)`

  • Assertion : PCl_(5) is covalent in gaseous and liquid state but ionic in solid state. Reason: PCl_(5) in solid state consists of tetrahedral PCl_(4)^(+) cation and octahedral PCl_(6)^(-) anion.

    A
    Both A and R are true and R is the correct explanation of A
    B
    Both A and R are true but R is false
    C
    A is true but R is false
    D
    A is false but R is true

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    PCl_5 has trigonal pyramidal geometry with sp^3 d hybridisation in gases and liquid state but in solid state it exist as ionic compound. In crystalline state PCl_5 exists as.

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