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At S.T.P., the density of nitrogen monox...

At S.T.P., the density of nitrogen monoxide is

A

`3.0 gL^(-1)`

B

`30gL^(-1)`

C

`1.3 gL^(-1)`

D

`2.68 gL^(-1)`

Text Solution

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The correct Answer is:
To find the density of nitrogen monoxide (NO) at standard temperature and pressure (STP), we can follow these steps: ### Step 1: Understand STP Conditions STP stands for Standard Temperature and Pressure. The standard temperature is 273.15 K, and the standard pressure is 1 bar (approximately 0.987 atm). ### Step 2: Determine the Molar Mass of Nitrogen Monoxide The molar mass of nitrogen monoxide (NO) can be calculated as follows: - Molar mass of Nitrogen (N) = 14 g/mol - Molar mass of Oxygen (O) = 16 g/mol - Therefore, Molar mass of NO = 14 g/mol + 16 g/mol = 30 g/mol ### Step 3: Use the Ideal Gas Equation to Find Density The ideal gas equation is given by: \[ PV = nRT \] Where: - \( P \) = pressure - \( V \) = volume - \( n \) = number of moles - \( R \) = ideal gas constant - \( T \) = temperature To find density (\( \rho \)), we can rearrange the equation: \[ \rho = \frac{PM}{RT} \] Where: - \( \rho \) = density - \( M \) = molar mass ### Step 4: Substitute Values into the Density Formula Using the values: - \( P = 0.987 \) atm (standard pressure) - \( M = 30 \) g/mol (molar mass of NO) - \( R = 0.0831 \) L·atm/(K·mol) (ideal gas constant) - \( T = 273.15 \) K (standard temperature) Substituting these values into the density formula: \[ \rho = \frac{(0.987 \, \text{atm}) \times (30 \, \text{g/mol})}{(0.0831 \, \text{L·atm/(K·mol)}) \times (273.15 \, \text{K})} \] ### Step 5: Calculate the Density Calculating the denominator: \[ 0.0831 \times 273.15 \approx 22.414 \, \text{L·atm/mol} \] Now substituting back into the density formula: \[ \rho = \frac{(0.987 \times 30)}{22.414} \approx \frac{29.61}{22.414} \approx 1.32 \, \text{g/L} \] ### Final Answer The density of nitrogen monoxide (NO) at STP is approximately **1.32 g/L**. ---
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