Home
Class 12
CHEMISTRY
What are the consequences that lead to t...

What are the consequences that lead to the development of quantum mechanical model of an atom?

Text Solution

Verified by Experts

In 1923 Louis de-Broglie proposed that like light matter also has dual character . It exhibits wave as well as particle nature . He derived an equation to calculate the wave-length `(lamda)` of the wave associated with a particle of mass m , nmoving with velocity v and it is given by
`lamda=(h)/("mv")" (or)"lamda=(h)/(p)`
'h' is Planck's constant and P is momentum of the particle . It may be noted that wave character has significance only in the case of sub-microscopic particles such as electrons.
The precise location of a wave cannot be predicted as a wave is not located at a particular point but extends in space . Thus the wave nature of electron puts some restriction in finding the position precisely . W . Heisenberg put forward this limitation in the form of uncertainty principle . According ot Heisenberg,
"It is not possible to determine simultaneously and accurately both the position and momentum of a small moving particle , such as electron."
It can be expressed mathematically as ,
`Delta"x"xxDeltapge(h)/(4pi)`
`Delta"x"xxmDeltavge(h)/(4pi)`
where `Deltax` = uncertainty in position
`Deltap` = uncertainty in momentum
m = mass of particle
`Deltav` = uncertainty in velocity
h = Planck's constant.
The uncertainty principle is due to the direct consequence of dual nature of matter .
A microscopic object such as electron has both observable wave - like and particle - like properties . The behaviour of such particles cannot be explained on the basis of science called quantum mechanical model of atom was developed . Quantum mechanics is a theroretical science that takes into account the dual nature of matter .
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    VGS PUBLICATION-BRILLIANT|Exercise ADDITIONAL QUESTIONS & ANSWERS|22 Videos
  • ATOMIC STRUCTURE

    VGS PUBLICATION-BRILLIANT|Exercise SHORT ANSWER QUESTIONS|18 Videos
  • AP MARCH-2018 I.P.E. PAPER

    VGS PUBLICATION-BRILLIANT|Exercise SECTION-C|5 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    VGS PUBLICATION-BRILLIANT|Exercise LONG ANSWER QUESTIONS|9 Videos

Similar Questions

Explore conceptually related problems

Who developed quantum mechanical model of atom ?

Explain the quantum mechanical model of an atom.

The basis of quantum mechanical model of an atom is

What are the main features of quantum mechanical model of an atom?

What are the consequences of deforestation ?

Quantum mechanical model of an atom was developed

Which of the following is true according to quantum mechanical model of an atom?

In Bohr model of atom :